太行山南段洪山沟铜金矿床白云母和绿泥石特征及其找矿意义-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

太行山南段洪山沟铜金矿床白云母和绿泥石特征及其找矿意义

Characteristics of muscovite and chlorite in Hongshangou copper-gold deposit and its prospecting significance

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DOI	10.20086/j.cnki.yskw.2025.4189
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2025, 44(4)
作者	王凯迪，张娟*，王红，刘新星，张勇，王丽杰，李若丹，关子琼，薛宇,
作者单位	1. 河北省战略性关键矿产研究协同创新中心, 河北地质大学, 河北石家庄 050031; 2. 河北省战略性关键矿产资源重点实验室, 河北地质大学, 河北石家庄 050031; 3. 河北省地矿局第九地质大队, 河北邢台 054000; 4. 内蒙古自治区地质调查研究院, 内蒙古呼和浩特 010041
摘要	洪山沟斑岩型铜金矿床是洪山多金属成矿区的典型矿床,位于华北克拉通中部南缘山西断隆武安凹陷区,矿体主要赋存于洪山正长斑岩体内。矿化中心及外围白云母和绿泥石十分发育。为探讨洪山沟铜金矿床白云母和绿泥石的成岩成矿意义,运用电子探针(EPMA)、激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)分析了矿床中不同产状和成矿阶段的白云母和绿泥石。结果显示,矿区内绿泥石根据其分布特征可分为3类: 与金属矿物共(伴)生的绿泥石(Chl-1)、由角闪石蚀变而成的绿泥石(Chl-2)及由黑云母蚀变而成的绿泥石(Chl-3)。3种绿泥石均为Fe绿泥石,指示形成于还原环境,其结构中存在Fe对Mg的置换以及Si对Al^Ⅳ的置换,表明绿泥石的形成受富Fe、Mg的成矿流体影响,由地质温度计计算出的绿泥石形成温度在112~272℃之间,属于中-低温热液蚀变范围。LA-ICP-MS结果显示完全蚀变的绿泥石更富Cu、Sn、Rb、Zn、Ti、Li、Sr、V、Co、Ni、Sn; 白云母主要有原生白云母(Ms-1)与次生白云母(Ms-2)两类,分别属于普通白云母和多硅白云母。与矿化密切相关的白云母具高Si、Fe低Al的特征,LA-ICP-MS结果显示还原环境下形成的白云母较氧化环境下形成的白云母更富V、W,暗示流体后期有大气降水的混入。综合本文研究成果认为,洪山沟铜金矿床成矿流体早期呈酸性,后期有大气降水的混入并逐渐向中性转变,铜金矿化成矿环境为近中性、还原的中-低温环境,成矿流体富Fe、Mg,贫Si。
Abstract	The Hongshangou porphyry copper-gold deposit is a typical deposit in the Hongshan polymetallic metallogenic area. It is located in the Wu'an depression of Shanxi fault uplift in the southern margin of the central North China Craton. The ore body mainly occurs in the Hongshan syenite porphyry. Muscovite and chlorite are well developed in the mineralization center and periphery. In order to discuss the diagenesis and mineralization significance of muscovite and chlorite in Hongshangou copper-gold deposit, electron probe microanalysis (EPMA) was used to analyze muscovite and chlorite in different occurrences and metallogenic stages of the deposit. The results show that the distribution characteristics of chlorite in the mining area can be divided into three categories: chlorite associated with metal minerals (Chl-1), chlorite altered from hornblende (Chl-2) and chlorite altered from biotite (Chl-3). The three chlorites are all Fe chlorites, indicating that they were formed in a reducing environment. The replacement of Fe to Mg and the replacement of Si to Al^Ⅳ in the structure indicate that the formation of chlorites is affected by Fe- and Mg-rich ore-forming fluids. The formation temperature of chlorite calculated by geological thermometer is between 112~272℃, which belongs to the range of medium-low temperature hydrothermal alteration, LA-ICP-MS results show that the completely altered chlorite is richer in Cu, Sn, Rb, Zn, Ti, Li, Sr, V, Co, Ni and Sn. Muscovite mainly includes primary muscovite (Ms-1) and secondary muscovite (Ms-2), which belong to ordinary muscovite and polysilicic muscovite respectively. The muscovite closely related to mineralization has the characteristics of high Si, Fe and low Al, LA-ICP-MS results show that the muscovite formed in the reducing environment is richer in V and W than the muscovite formed in the oxidizing environment, suggesting the mixing of meteoric water in the later stage of the fluid. Based on the research results of this paper, the ore-forming fluid of Hongshangou copper-gold deposit is acidic in the early stage and gradually changes to neutral in the later stage. The ore-forming environment of copper-gold deposit is near neutral and reduced medium-low temperature environment. The ore-forming fluid is rich in Fe, Mg and poor in Si.
关键词	白云母；绿泥石；电子探针；洪山沟铜金矿床；华北克拉通
KeyWord	muscovite; chlorite; electron probe microanalysis; Hongshangou porphyry copper-gold deposit; North China Craton
基金项目
页码	924-948

参考文献
相关文献

Adegoke I A, Xia F, Deditius A P, et al. 2022. A new mode of mineral replacement reactions involving the synergy between fluid-induced solid-state diffusion and dissolution-reprecipitation: A case study of the replacement of bornite by copper sulfides
[J]. Geochimica et Cosmochimica Acta, 330: 165~190.
Ai Yongfu and Liu Guoping. 1998. The study of chlorite at Dajing deposit in Innrer-Mongolia of China
[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 34(1): 99~107 (in Chinese with English abstract).
Alva-Jimenez T, Tosdal R M, Dilles J H, et al. 2020. Chemical variations in hydrothermal white mica across the Highland Valley porphyry Cu-Mo district, British Columbia, Canada
[J]. Economic Geology, 115(4): 903~926.
Ayuso R A. 1987. White Mica Geochemistry of the Catheart Mountain Porphyry Copper Deposit, Maine
[R]. US Government Printing Office.
Bai Fusheng. 2022. Study on the Genesis and Mineralization of Hongshan Complex in Han-Xing Area, Southern Hebei Province
[D]. Shijia-zhuang: Hebei Geology University (in Chinese with English abstract).
Basori M B I, Zaw K, McNeill A, et al. 2022. A mineralogical and geochemical application for determining hydrothermal alteration zones associated with volcanic-hosted massive sulphide deposits at Tasik Chini area, Peninsular Malaysia
[J]. Applied Geochemistry, 145(2): 105~404.
Battaglia S. 1999. Applying X-ray geothermometer diffraction to a chlorite
[J]. Clays and Clay Minerals, 47(1): 54~63.
Benavides S B. 2017. Characterisation of Sericitic Alteration at the Taca Bajo Porphyry Cu Deposit, Argentina
[D]. University of Tasmania.
Bryndzia L T and Scott S D. 1987. The composition of chlorite as a function of sulfur and oxygen fugacity: An experimental study
[J]. American Journal of Science, 287(1): 50~76.
Cathelineau M. 1988. Cation site occupancy in chlorites and illites as a function of temperature
[J]. Clay Minerals, 23(4): 471~485.
Cathelineau M and Nieva D. 1985. A chlorite solid solution geothermometer the Los Azufres (Mexico) geothermal system
[J]. Contributions to Mineralogy and Petrology, 91(3): 235~244.
Černý P, Chapman R, Teertstra D K, et al. 2003. Rubidium and cesium dominant micas in granitic pegmatites
[J]. American Mineralogist, 88(12): 1 832~1 835.
Chaffee M A. 1982. A geochemical study of the Kalamazoo porphyry copper deposit, Pinal County, Arizona
[J]. Advances in Geology of the Porphyry Copper Deposits; Titley, SR, Ed: 211~225.
Chang Hao, Zhang Liangliang and Yue Peng. 2020. Preliminary study on geological characteristics and genesis of Hongshangou copper deposit in Handan City
[J]. China Metal Bulletin, (1): 37, 39 (in Chinese with English abstract).
Chang Hao, Zhang Liangliang, Yue Peng, et al. 2017. Preliminary Survey Report on the Hongshangou Copper and Polymetallic Deposit in Wu'an City, Hebei Province
[R]. Ninth Geology Division of Hebei Bureau of Geology and Mineral Resources Exploration(in Chinese).
Chang J, Li J W and Audétat A. 2018. Formation and evolution of multistage magmatic-hydrothermalfluids at the Yulong porphyry Cu-Mo deposit, eastern Tibet: Insights from LA-ICP-MS analysis of fluid inclusions
[J]. Geochimica et Cosmochimica Acta, 232: 181~205.
Chen Yanjing, Ni Pei, Fan Hongrui, et al. 2007. Diagnostic fluid inclusions of different types hydrothermal gold deposits
[J]. Acta Petrologica Sinica, 23 (9): 2 085~2108 (in Chinese with English abstract).
Chu G, Zhang S, Zhang X, et al. 2020. Chlorite chemistry of Tongshankou porphyry-related Cu-Mo-W skarn deposit, Eastern China: Implications for hydrothermal fluid evolution and exploration vectoring to concealed orebodies
[J]. Ore Geology Reviews, 122: 103531.
Chu Xiangkai, Shen Ping, Li Changhao, et al. 2023. Ore-forming fluid evolution of the Wunugetushan porphyry Cu-Mo deposit, Inner Mongolia: Evidence from the short-wave infrared spectrum, mica composition and fluid inclusion of quartz
[J]. Acta Petrologica Sinica, 39 (11): 3 461~3 478 (in Chinese with English abstract).
Cui Xiaoliang, Su Shangguo, Zhang Yanan, et al. 2022. Deep magmatic process of the Fushan complex in the southern section of Taihang Mountain, Hebei Province and its tectonic significance
[J]. Earth Science Frontiers, 29(1): 342~363 (in Chinese with English abstract).
Duke E F. 1994. Near infrared spectra of muscovite, Tschermak substitution, and metamorphic reaction progress: Implications for remote sensing
[J]. Geology, 22(7): 621~624.
Feng Y, Chu G, Xiao B, et al. 2022. Chlorite mineralogy, geochemistry and exploration implications: A case study of the Xiaokelehe porphyry Cu-Mo deposit in NE China
[J]. Ore Geology Reviews, 140: 104~568.
Fu Jiangang, Li Guangming, Guo Weikang, et al. 2023. Mineral geochemical characteristics of muscovite and its implication for rare metal mineralization in leucogranites in the Lalong Dome, Xizang, China
[J]. Journal of East China University of Technology (Natural Science), 46(6): 555~575 (in Chinese with English abstract).
Ge Xiangkun, Ju Haiyu, Zhao Fenghua, et al. 2020. Characteristics of chlorites in the Shangdajing porphyry Mo deposit, Inner Mongolia and their metallogenic implications
[J]. Geology and Exploration, 56(4): 704~713 (in Chinese with English abstract).
Geng Guojian, Ma Baojun and Shen Fangle. 2023. Geological characteristics and mineralization of Taoyuan copper deposit in south part of Taihang Mountain
[J]. Journal of Hebei GEO University, 46(4): 90~100 (in Chinese with English abstract).
Guidotti C V, Sassi F P, Blencoe J G, et al. 1994. The paragonite muscovite solvus: I. PTX limits derived from the Na-K compositions of natural, quasibinary paragonite muscovite pairs
[J]. Geochimica et Cosmochimica Acta, 58(10): 2 269~2 275.
Guo Guolin, Liu Xiaodong, Pan Jiayong, et al. 2012. Character of chlorite and its relationship to uranium mineralization in uranium deposit No.302
[J]. Uranium Geology, 28(1): 35~41 (in Chinese with English abstract).
Guo Na, Huang Yiru, Zheng Long, et al. 2017. Alteration zoning and prospecting model of epithermal deposit revealed by shortwave infrared technique: A case study of Tiegelongnan and Sinongduo Deposits
[J]. Acta Geoscientica Sinica, 38(5): 767~778 (in Chinese with English abstract).
Halley S, Dilles J H and Tosdal R M. 2015. Footprints: Hydrothermal alteration and geochemical dispersion around porphyry copper deposits
[J]. SEG Newsletter, 100(1): 1~17.
He Wen, Lin Bin, Song Yingxin, et al. 2023. Mineralogical characteristics and implications of muscovite from the Tiegelongnan super-large copper (gold) deposit in Tibet
[J]. Acta Geologica Sinica, 97(6): 1 938~1 955 (in Chinese with English abstract).
Hemley J J and Jones W R. 1964. Chemical aspects of hydrothermal alteration with emphasis on hydrogen metasomatism
[J]. Economic Geology, 59(4): 538~569.
Hillier S. 1993. Origin, diagenesis, and mineralogy of chlorite minerals in Devonian lacustrine mudrocks, Orcadian Basin, Scotland
[J]. Clays and Clay Minerals, 41(2): 240~259.
Hiller S and Velde B. 1991. Octahedral occupancy and the chemical composition of diagenetic (low-temperature) chlorites
[J]. Clay Minerals, 26: 149~168.
Hou Zengqian, Pan Xiaofei, Yang Zhiming, et al. 2007. Porphyry Cu-(Mo-Au) deposits no related to oceanic-slab subduction: Examples from Chinese porphyry deposits in continental settings
[J]. Geoscience, 21(2): 332~351 (in Chinese with English abstract).
Hou Z Q, Yang Z M, Lü Y J, et al. 2015. A genetic linkage between subduction and collision-related porphyry Cu depsits in continental collision zones
[J]. Geology, 43(3): 247~250.
Inoue A. 1952. Formation of Clay Mineralsin Hydrothermal Environments Veide. Origin and Mineralogy of Clays
[M]. Berlin: Springer, 268~330.
Inoue A. 1995. Formation of clay minerals in hydrothermal environments
[J]. Origin and Mineralogy of Clays: Clays and the Environment, 268~329.
Inoue A, Meunier A, Patrier M P, et al. 2009. Application of chemical geothermometry to low-temperature trioctahedral chlorites
[J]. Clays and Clay Minerals, 57(3): 371~382.
Jago C P, Tosdal R M, Cooke D R, et al. 2014. Vertical and lateral variation of mineralogy and chemistry in the Early Jurassic Mt. Milligan alkalic porphyry Au-Cu deposit, British Columbia, Canada
[J]. Economic Geology, 109(4): 1 005~1 033.
Jowett E C. 1991. Fitting iron and magnesium into the hydrothermalchlorite geothermometer: Program with abstracts
[J]. Geological Association of Canada, 16: 62.
Kavalieris I, Walshe J L, Halley S, et al. 1990. Dome-related gold mineralization in the Pani volcanic complex, North Sulawesi, Indonesia; A study of geologic relations, fluid inclusions, and chlorite compositions
[J]. Economic Geology, 85(6): 1 208~1 225.
Keppler H. 1993. Influence of fluorine on the enrichment of high field strength trace elements in granitic rocks
[J]. Contributions to Mineralogy and Petrology, 114: 479~488.
Kranidiotis P and MacLean W H. 1987. Systematics of chlorite alteration at the Phelps Dodge massive sulfide deposit, Matagami, Quebec
[J]. Economic Geology, 82(7): 1 898~1 911.
Laakso K, Peter J M, Rivard B, et al. 2016. Short-wave infrared spectral and geochemical characteristics of hydrothermal alteration at the Archean Izok Lake Zn-Cu-Pb-Ag volcanogenic massive sulfide deposit, Nunavut, Canada: Application in exploration target vectoring
[J]. Economic Geology, 111(5): 1 223~1 239.
Laird J. 1988. Chlorites: Metamorphic petrology
[J]. Reviews in Mineralogy, 19(1): 405~453.
Legros H, Marignac C, Tabary T, et al. 2018. The ore forming magmatic-hydrothermal system of the Piaotang W-Sn deposit (Jiangxi, China) as seen from Li-mica geochemistry
[J]. American Mineralogist, 103(1): 39~54.
Li C, Shen P, Zhao Y, et al. 2022. Mineral chemistry of chlorite in different geologic environments and its implications for porphyry Cu±Au±Mo deposits
[J]. Ore Geology Reviews, 149: 105~112.
Li Faqiao, Tang Juxing, Song Yang, et al., 2024. Mineralogical characteristics and geological significance of apatite in the Naruo porphyry Cu (Au) deposit in Duolong ore district, northwestern Xizang (Tibet)
[J]. Geological Review, 70(3): 885~906 (in Chinese with English abstract).
Li J, Huang X L, He P L, et al. 2015. In situ analyses of micas in the Yashan granite, South China: Constraints on magmatic and hydrothermal evolutions of W and Ta-Nb bearing granites
[J]. Ore Geology Reviews, 65(4): 793~810.
Li Jinwen, Zhang Dequan, Zhao Shibao, et al. 2006. Metallogenic regularity and prospecting targets in the southwest part of the Derbugan metalloginic belt
[J]. Mineral Deposits, 25(S1): 19~22 (in Chinese with English abstract).
Li Suimin, Li Yucheng, Zhao Shumei, et al. 2022. Ar-Ar and U-Pb ages of Hongshan copper deposit, Handan City, Hebei Province and their limitation on mineralization age
[J]. Geology in China, 49(2): 575~585 (in Chinese with English abstract).
Li Yucheng, Jia Liqin, Zhao Shumei, et al. 2016. Lithographic characteristics of Hongshan volcanic edifice in the southern section of Taihang Mountains
[J]. Modern Mining, 32(5): 142~145 (in Chinese with English abstract).
Li Z K, Li J W, Zhao X F, et al. 2013. Crustal extension Ag-Pb-Zn veins in the Xiong’ershan District, Southern North China craton: Constraints from the Shagou deposit
[J]. Economic Geology, 108(7): 1 703~1 729.
Li Ziye, Xing Huan, Li Suimin, et al. 2017. Fluid inclusions test of Louli gold deposit and their geological significance
[J]. Contributions to Geology and Mineral Resources Research, 32(2): 205~213 (in Chinese with English abstract).
Liu Songyan, Zhang Da, Yang Mingjian, et al. 2024. Characteristics of chlorites from the Haopinggou Ag-Au polymetallic deposit in the Xiong’ershan ore concentration area and its exploration implications
[J]. Journal of Geomechanics, 30(1): 129~146 (in Chinese with English abstract).
Liu Xinyao. 2016. Petrogensis and Metallogeny of Hongshan Orthophyrein Southern Taihang Mountain
[D]. China University of Geosciences (in Chinese with English abstract).
Loucks R R. 2014. Distinctive composition of copper ore forming arcmagmas
[J]. Australian Journal of Earth Sciences, 61(1): 5~16.
Ma Wanwei, Huang Xiaolong, Yu Yang, et al. 2020. Characteristics of micas in the Limu granites, South China: An indicator of the hydrothermal processes related to tin mineralization
[J]. Geotectonica et Metallogenia, 44(6): 1 143~1 159 (in Chinese with English abstract).
Mallmann G and O’Neill H S C. 2013. Calibration of an empirical thermometer and oxybarometer based on the partitioning of Sc, Y and V between olivine and silicate melt
[J]. Journal of Petrology, 54(5): 933~949.
Mernagh T P, Leys C and Henley R W. 2020. Fluid inclusion systematics in porphyry copper deposits: The super-giant Grasberg deposit, Indonesia, as a case study
[J]. Ore Geology Reviews, 123: 103~570.
Miller C F, Stoddard E F, Bradfish L J, et al. 1981. Composition of plutonic muscovite: Genetic implications
[J]. Canadian Mineralogist, 19(1): 25~34.
Monier G, Mergoil D J and Labernadière H. 1984. Générations successives de muscovites et feldspaths potassiques dans les leucogranites du massif de Millevaches (Massif Central Français)
[J]. Bulletin de Minéralogie, 107(1): 55~68.
Neiva A M R. 2013. Micas, feldspars and columbite-tantalite minerals from the zoned granitic lepidolite-subtype pegmatite at Namivo, Alto Ligonha, Mozambique
[J]. European Journal of Mineralogy, 25(6): 967~985.
Ohmoto H. 1997. Applications of sulfur and carbon isotopes in ore deposit research
[J]. Geochemistry of Hydrothermal Ore Deposits, 517~611.
Pacey A, Wilkinson J J and Cooke D R. 2020. Chlorite and epidote mineral chemistry in porphyry ore systems: A case study of the Northparkes district, New South Wales, Australia
[J]. Economic Geology, 115(4): 701~727.
Pak S J, Choi S G and Choi S H. 2004. Systematic mineralogy and chemistry of gold silver vein deposits in the Taebaeksan district, Korea: Distal relatives of a porphyry system
[J]. Mineralogical Magazine, 68(3): 467~487.
Portela B, Sepp M D, van F J A, et al. 2021. Using hyperspectral imagery for identification of pyrophyllite muscovite intergrowths and alunite in the shallow epithermal environment of the Yerington porphyry copper district
[J]. Ore Geology Reviews, 131(1): 104012.
Quan Rui, Dong Guochen, Miu Guang, et al. 2016. Zircon U-Pb ages, Hf isotopic compositions and geochemistry characterisitics of the Hongshan ore-bearing syenite porphyries from Southern Taihang Mountains
[J]. Geological Review, 62(4): 1 064~1 080 (in Chinese with English abstract).
Richards J P. 2015. The oxidation state, and sulfur and Cu contents of arc magmas: Implications for metallogeny
[J]. Lithos, 23(3): 27~45.
Richards J P, Spell T, Rameh E, et al. 2012. High Sr/Y magmas reflect arc maturity, high magmatic water content, and porphyry Cu±Mo±Au potential: Examples from the Tethyan arcs of central and eastern Iran and western Pakistan
[J]. Economic Geology, 107(2): 295~332.
Schirra M, Laurent O, Zwyer T, et al. 2022. Fluid evolution at the Batu Hijau porphyry Cu-Au deposit, Indonesia: Hypogene sulfide precipitation from a single phase aqueous magmatic fluid during chlorite white-mica alteration
[J]. Economic Geology, 117(5): 979~1 012.
Shi Zhiwei, Dong Guochen, Gao Ting, et al. 2020. Mineralogical characteristics of Jiaochang diorite in Southern Taihang Mountains and geological significance
[J]. Earth Science, 45(6): 2 103~2 116 (in Chinese with English abstract).
Sillitoe R H. 1972. A plate tectonic model for the origin of porphyry copper deposits
[J]. Economic Geology, 67(2): 184~197.
Sillitoe R H. 2010. Porphyry copper systems
[J]. Economic Geology, 105(1): 3~41.
Sun W D, Huang R, Li H, et al. 2015. Porphyry deposits and oxidized magmas
[J]. Ore Geology Reviews, 65(1): 97~131.
Sun W D, Liang H, Ling M, et al. 2013. The link between reduced porphyry copper deposits and oxidized magmas
[J]. Geochimica et Cosmochimica Acta, 103: 263~275.
Tang Nan, Lin Bin, Li Yubin, et al. 2021. Application of short-wavelength infrared spectroscopy in porphyry-epithermal system: A case study of Tiegelongnan super-large copper (gold) deposit, Tibet
[J]. Acta Geologica Sinica, 95(8): 2 613~2 627 (in Chinese with English abstract).
Thompson A J, Hauff P L and Robitaille A J. 2009. Alteration mapping in exploration: Application of short-wave infrared (SWIR) spectroscopy
[J]. Remote Sensing and Spectral Geology, 16: 25~40.
Tian Chenghua, Yang Liqiang, He Wenyan, et al. 2022. Characteristics of short wave infrared spectroscopy of sericite group minerals and their implications for exploration in the Yulong porphyry copper deposit, Tibet
[J]. Sedimentary Geology and Tethyan Geology, 42(1): 40~49 (in Chinese with English abstract).
Tischendorf G, Förster H J and Gottesmann B. 1999. The correlation between lithium and magnesium in trioctahedral micas: Improved equations for Li₂O estimation from MgO data
[J]. Mineralogical Magazine, 63(1): 57~74.
Tischendorf G, Gottesmann B, Förster H J, et al. 1997. On Li bearing micas: Estimating Li from electron microprobe analyses and an improved diagram for graphical representation
[J]. Mineralogical Magazine, 61(409): 809~834.
Uribe-Mogollon C and Maher K. 2018. White mica geochemistry of the copper cliff porphyry Cu deposit: Insights from a vectoring tool applied to exploration
[J]. Economic Geology, 113(6): 1 269~1 295.
Uribe-Mogollon C and Maher K. 2020. White mica geochemistry: Discriminating between barren and mineralized porphyry systems
[J]. Economic Geology, 115(2): 325~354.
Wang Baohua, Hu Rongguo, Si Jiantao, et al. 2021. Chemical variation and significance of white mica in granite porphyry from Gaofeng tin-polymetallic deposit in Dachang ore field, Guangxi
[J]. Journal of Guilin University of Technology, 41(3): 471~483 (in Chinese with English abstract).
Wang Chunguang, Xu Wenliang, Wang Feng, et al. 2011. Petrogenesis of the Early Cretaceous Xi’anli hornblende-gabbros from the Southern Taihang Mountains: Evidence from zircon U-Pb geochronology, Hf isotope and whole-rock geochemistry
[J]. Earth Science, 36(3): 471~482 (in Chinese with English abstract).
Wang Wei, Leng Chengbiao, Zhang Xingchun, et al. 2021. Mineral chemistry of chlorite and epidote in Diyanqinamu porphyry Mo deposit of Inner Mongolia and its implication for exploration
[J]. Mineral Deposits, 40 (2): 241~261 (in Chinese with English abstract).
Wang Xiaoyu, Mao Jingwen, Cheng Yanbo, et al. 2014. Characteristics of chlorite from the Xinliaodong Cu polymetallic deposit in eastern Guangdong Province and their geological significance
[J]. Acta Petrologica et Mineralogica, 33(5): 885~905 (in Chinese with English abstract).
Wang Y H, Zhang F F, Liu J J, et al. 2018. Ore genesis and hydrothermal evolution of the Donggebi porphyry Mo deposit, Xinjiang, Northwest China: Evidence from isotopes (C, H, O, S, Pb), fluid inclusions, and molybdenite Re-Os dating
[J]. Economic Geology, 113(2): 463~488.
Wiewióra A and Weiss Z. 1990. Crystally chemical classifications of phyllosilicates based on the unified system of projection of chemical composition: II. The chlorite group
[J]. Clay minerals, 25(1): 83~92.
Wilkinson J J, Chang Z, Cooke D R, et al. 2015. The chlorite proximitor: A new tool for detecting porphyry ore deposits
[J]. Journal of Geochemical Exploration, 152: 10~26.
Wu D, Pan J, Xia F, et al. 2019. The mineral chemistry of chlorites and its relationship with uranium mineralization from Huangsha uranium mining area in the Middle Nanling Range, SE China
[J]. Minerals, 9(3): 199~222.
Wu Fuyuan, Xu Yigang, Gao Shan, et al. 2008. Lithospheric thinning and major destruction of the North China Craton
[J]. Acta Petrologica Sinica, 24(6): 1 145~1 174 (in Chinese with English abstract).
Xi Chaozhuang, Du Gaofeng, Dai Xueling, et al. 2021. Geochemistry and chronology characteristics of Kuangshan complex in the southern Taihang Mountain and the geological significance
[J]. Contributions to Geology and Mineral Resources Research, 36(3): 308~317 (in Chinese with English abstract).
Xiao B and Chen H. 2020. Elemental behavior during chlorite alteration: New insights from a combined EMPA and LA-ICP-Ms study in porphyry Cu systems
[J]. Chemical Geology, 543(2): 119~604.
Xiao B, Chen H, Hollings P, et al. 2018. Element transport and enrichment during propylitic alteration in Paleozoic porphyry Cu mineralization systems: Insights from chlorite chemistry
[J]. Ore Geology Reviews, 102(1): 437~448.
Xie X, Byerly G R and Ferrell Jr R E. 1997. IIb trioctahedral chlorite from the Barberton greenstone belt: Crystal structure and rock composition constraints with implications to geothermometry
[J]. Contributions to Mineralogy and Petrology, 126(1): 275~291.
Xu Wenliang and Gao Yan. 1990a. Rare earth element geochemistry of intrusive rock series of Yanshan stage from Han-Xing district, Hebei Province, China
[J]. Acta Petrologica Sinica, 6(2): 43~50 (in Chinese with English abstract).
Xu Wenliang and Lin Jingqian. 1990b. The magmatic evolution of Hb-diorite series of Yanshan stage in Han-Xing district, China—The amphibole-dominated fractional crystallization
[J]. Journal of Jilin University (Earth Science Edition), 20(3): 259~264 (in Chinese with English abstract).
Xu Y G. 2001. Thermo tectonic destruction of the Archaean lithospheric keel beneath the Sino-Korean Craton in China: Evidence, timing and mechanism
[J]. Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy, 26(9~10): 747~757.
Xue Q, Wang R, Liu S, et al. 2021. Significance of chlorite hyperspectral and geochemical characteristics in exploration: A case study of the giant Qulong porphyry Cu-Mo deposit in collisional orogen, Southern Tibet
[J]. Ore Geology Reviews, 134: 104~156.
Yang C, Beaudoin G, Tang J X, et al. 2022. Cu-sulfide mineralogy, texture, and geochemistry in the Tiegelongnan porphyry-epithermal copper system, Tibet, China
[J]. Mineralium Deposita, 57: 1~21.
Yang Changqing, Ba Yan, Wang Yanhui, et al. 2023. Ordovician magmatism in the North China Craton—Evidence from U-Pb age of the inherited zircon from Cretaceous diorite in Lingtou area, Anyang, Henan
[J]. Geological Review, 69(3): 1 150~1 160 (in Chinese with English abstract).
Yang Hang, Qin Kezhang, Wu Peng, et al. 2023. Tectonic setting, mineralization and ore-controlling factors of porphyry Cu-Mo-Au deposits
[J]. Mineral Deposits, 42(1): 128~156 (in Chinese with English abstract).
Yao Shixin, Wu Liangshi and Pei Rongfu. 1993. Geological, geochemical and mineralization characteristics of Hongshan intrusive complex in Handan-Xingtai Area, Hebei Province
[J]. Geology and Exploration, 5(1): 11~16 (in Chinese with English abstract).
Ye Meifang, Liu San, Xie Guwei, et al. 2016. Characteristics of micas from sericitolite of the Gongpoquan and Baishantang deposits, Beishan area by scanning electron microscope, X-ray diffraction and electron microprobe analyses
[J]. Rock and Mineral Analysis, 35(2): 166~177 (in Chinese with English abstract).
Yin Ming, Guo Min and Zhang Haidong. 2014. Petrogenesis and evolution of Mesozoic complexes from Southern Taihang Orogen
[J]. Northwestern Geology, 47(3): 43~53 (in Chinese with English abstract).
Yin R, Han L, Huang X L, et al. 2019. Textural and chemical variations of micas as indicators for tungsten mineralization: Evidence from highly evolved granites in the Dahutang tungsten deposit, South China
[J]. American Mineralogist, 104(7): 949~965.
Zane A and Weiss Z. 1998. A procedure for classifying rock-forming chlorites based on microprobe data; Una procedura per la classificazione delle cloriti sulla base di dati microchimici
[J]. Atti della Accademia Nazionale dei Lincei. Rendiconti. Scienze Fisiche e Naturali, 9.
Zang W and Fyfe W S. 1995. Chloritization of the hydrothermally altered bedrock at the Igarapé Bahia gold deposit, Carajás, Brazil
[J]. Mineralium Deposita, 30(1): 30~38.
Zeng Shuming, Zhang Yan, Han Runsheng, et al. 2023. Characteristics and geological significance of chlorite in Wengkongba copper polymetallic deposit, southwestern Yunnan
[J]. Mineral Deposits, 42(4): 828~844 (in Chinese with English abstract).
Zhai Mingguo, Fan Qicheng, Zhang Hongfu, et al. 2005. Lower crust processes during the lithosphere thinning in eastern China: Magma underplating, replacement and delamination
[J]. Acta Petrologica Sinica, 21(6): 1 509~1 526 (in Chinese with English abstract).
Zhang Bo, Su Shangguo, Wang Guodong, et al. 2020. Mineral chemistry of clinopyroxene from the Hongshan syenite complex in Wu'an, Hebei Province: Implications for magma evolution
[J]. Geology in China, 47(3): 782~797 (in Chinese with English abstract).
Zhang Haidong, Liu Jianchao, Chen Zhengle, et al. 2014. Petrogensis of the Pingshun complexes in the Southern Taihang Mountains: Petrology, geochronology and geochemistry
[J]. Geotectonica et Metallogenia, 38(2): 454~471 (in Chinese with English abstract).
Zhang Juan, Liu Xinxing, Wang Yitian, et al. 2021. Characteristics of chlorite from the Baguamiao gold deposit in Shaanxi Province and its geological implication
[J]. Geological Bulletin of China, 40(4): 586~603 (in Chinese with English abstract).
Zhang S, Xiao B, Long X, et al. 2020. Chlorite as an exploration indicator for concealed skarn mineralization: Perspective from the Tonglushan Cu-Au-Fe skarn deposit, Eastern China
[J]. Ore Geology Reviews, 126: 103~778.
Zhang W, Zhang F F, Wang Y H, et al. 2022. Chlorite chemistry, HOS-Pb isotopes and fluid characteristics of the Yuhai Cu-Mo Deposit in Eastern Tianshan: Implications for porphyry copper mineralization and exploration
[J]. Journal of Geochemical Exploration, 241: 59~107.
Zhang Zhanshi, Hua Renmin, Ji Junfeng, et al. 2007. Characteristics and formation conditions of chlorite in No.201 and No.361
[J]. Acta Mineralogica Sinica, 27(2): 161~172 (in Chinese with English abstract).
Zhao Youdong, Wu Junqi, Ling Hongfei, et al. 2016. Mineral chemistry of biotite and chlorite in western part of Fucheng granite, southern Jiangxi Province: Implications for uranium mineralization
[J]. Mineral Deposits, 35(1): 153~168 (in Chinese with English abstract).
Zhou Dong, Zhao Taiping, Zhao Pengbin, et al. 2018. Chlorite EPMA characteristic and its geological significance of the Kangshan Au-Ag-Pb-Zn deposit in west of Henan
[J]. Mineral Exploration, 9(5): 803~824 (in Chinese with English abstract).
Zhou Ling and Chen Bin. 2005. Petrogenesis and significance of the Hongshan syenite in the South Taihang Mountains: Zircon SHRIMP geochronology, chemical composition and Sr-Nd isotopic characteristics
[J]. Progress in Natural Science, 11(1): 1 357~1 365 (in Chinese with English abstract).
艾永富, 刘国平. 1998. 内蒙大井矿床的绿泥石研究
[J]. 北京大学学报(自然科学版), 34(1): 99~107.
白富生. 2022. 冀南邯邢地区洪山杂岩体成因及其成矿作用的研究
[D]. 石家庄: 河北地质大学.
常浩, 张良良, 岳鹏. 2020. 邯郸市洪山沟铜矿地质特征及成因初探
[J]. 中国金属通报, (1): 37, 39.
常浩, 张良良, 岳鹏, 等. 2017. 河北省武安市洪山沟铜及多金属矿预查报告
[R]. 河北省第九地质大队.
陈衍景, 倪培, 范宏瑞, 等. 2007.不同类型热液金矿系统的流体包裹体特征
[J]. 岩石学报, 23(9): 2 085~2 108.
楚翔凯, 申萍, 李昌昊, 等. 2023. 内蒙古乌努格吐山斑岩铜钼矿床成矿流体演化——基于短波红外光谱、云母成分和石英流体包裹体研究
[J]. 岩石学报, 39(11): 3 461~3 478.
崔晓亮, 苏尚国, 张雅南, 等. 2022. 河北太行山南段符山杂岩体岩浆作用深部过程及其大地构造意义
[J].地学前缘, 29(1): 342~363.
付建刚, 李光明, 郭伟康, 等. 2023. 西藏拉隆穹窿淡色花岗岩中白云母矿物地球化学特征及对稀有金属成矿的指示
[J]. 东华理工大学学报(自然科学版), 46(6): 555~575.
葛祥坤, 句海玉, 赵峰华, 等. 2020. 内蒙古上打井斑岩型钼矿床绿泥石特征及成矿意义
[J]. 地质与勘探, 56(4): 704~713.
耿国建, 马宝军, 申方乐. 2023. 太行山南段桃园铜矿地质特征及成矿作用
[J]. 河北地质大学学报, 46(4): 90~100.
郭娜, 黄一入, 郑龙, 等. 2017. 高硫-低硫化浅成低温热液矿床的短波红外矿物分布特征及找矿模型——以西藏铁格隆南(荣那矿段)、斯弄多矿床为例
[J]. 地球学报, 38(5): 767~778.
郭国林, 刘晓东, 潘家永, 等. 2012. 302铀矿床绿泥石特征及其与铀成矿的关系
[J]. 铀矿地质, 28(1): 35~41.
贺文, 林彬, 宋英昕, 等. 2023. 西藏铁格隆南超大型铜(金)矿床白云母矿物学特征及地质意义
[J]. 地质学报, 97(6): 1 938~1 955.
侯增谦, 潘小菲, 杨志明, 等. 2007. 初论大陆环境斑岩铜矿
[J]. 现代地质, 21(2): 332~351.
李发桥, 唐菊兴, 宋扬, 等. 2024. 藏西北多龙矿集区拿若斑岩铜(金)矿床磷灰石矿物学特征及地质意义
[J]. 地质论评, 70(3): 885~906.
李进文, 张德全, 赵士宝, 等. 2006. 得尔布干成矿带西南段金属成矿规律及找矿方向
[J]. 矿床地质, 25(S1): 19~22.
李随民, 李玉成, 赵淑梅, 等. 2022. 河北邯郸洪山铜矿Ar-Ar和U-Pb年龄及其对成矿时代的限定
[J]. 中国地质, 49(2): 575~585.
李玉成, 贾立芹, 赵书梅, 等. 2016. 太行山南段洪山火山机构岩相学特征
[J]. 现代矿业, 32(5): 142~145.
李紫烨, 邢欢, 李随民, 等. 2017. 娄里金矿床包裹体测试及地质意义
[J]. 地质找矿论丛, 32(2): 205~213.
刘松岩, 张达, 杨明建, 等. 2024. 熊耳山矿集区蒿坪Ag-Au多金属矿床绿泥石特征及其找矿意义
[J]. 地质力学学报, 30(1): 129~146.
刘昕曜. 2016. 太行山南段洪山正长斑岩成岩成矿作用
[D]. 北京: 中国地质大学(北京).
马万伟, 黄小龙, 于洋, 等. 2020. 栗木花岗岩中云母的特征: 对锡成矿热液作用过程的指示
[J].大地构造与成矿学, 44(6): 1 143~1 159.
权瑞, 董国臣, 缪广, 等. 2016. 太行山南段洪山矿化正长斑岩LA-ICP-MS锆石U-Pb年龄、Hf同位素组成及地球化学特征
[J]. 地质论评, 62(4): 1 064~1 080.
史志伟, 董国臣, 高庭, 等. 2020. 太行山南段教场闪长岩矿物学特征及其地质意义
[J]. 地球科学, 45(6): 2 103~2 116.
唐楠, 林彬, 李玉彬, 等. 2021. 短波红外光谱技术在斑岩-高硫化型浅成低温热液矿床中的应用——以西藏铁格隆南超大型铜(金)矿床为例
[J]. 地质学报, 95(8): 2 613~2 627.
田成华, 杨立强, 和文言, 等. 2022. 西藏玉龙斑岩铜矿床绢云母族蚀变矿物短波红外光谱特征及对勘查的指示意义
[J]. 沉积与特提斯地质, 42(1): 40~49.
王葆华, 胡荣国, 司建涛, 等. 2021. 广西大厂矿田高峰锡多金属矿床花岗斑岩白云母化学特征及其地质意义
[J]. 桂林理工大学学报, 41(3): 471~483.
王春光, 许文良, 王枫, 等. 2011. 太行山南段西安里早白垩世角闪辉长岩的成因: 锆石U-Pb年龄、Hf同位素和岩石地球化学证据
[J]. 地球科学, 36(3): 471~482.
王帏, 冷成彪, 张兴春, 等. 2021. 内蒙古迪彦钦阿木斑岩钼矿床绿泥石和绿帘石矿物化学特征及其成矿指示意义
[J]. 矿床地质, 40(2): 241~261.
王小雨, 毛景文, 程彦博, 等. 2014. 粤东新寮岽铜多金属矿床绿泥石特征及其地质意义
[J]. 岩石矿物学杂志, 33(5): 885~905.
吴福元, 徐义刚, 高山, 等. 2008. 华北岩石圈减薄与克拉通破坏研究的主要学术争论
[J]. 岩石学报, 24(6): 1 145~1 174.
息朝庄, 杜高峰, 戴雪灵, 等. 2021. 太行山南段矿山杂岩体LA-ICP-MS锆石U-Pb年代学、地球化学及其地质意义
[J]. 地质找矿论丛, 36(3): 308~317.
许文良, 高燕. 1990a. 邯邢地区燕山期侵入岩系的稀土元素特征
[J]. 岩石学报, 6(2): 43~50.
许文良, 林景仟. 1990b. 邯邢地区燕山期角闪闪长岩系的岩浆演化——角闪石占主导的矿物分离结晶作用
[J].长春地质学院学报, 20(3): 259~264.
杨长青, 巴燕, 王艳慧, 等. 2023. 华北克拉通奥陶纪岩浆活动——来自河南安阳岭头地区白垩纪闪长岩中继承锆石U-Pb年龄的证据
[J]. 地质论评, 69(3): 1 150~1 160.
杨航, 秦克章, 吴鹏, 等. 2023. 斑岩铜-钼-金矿床: 构造环境、成矿作用与控制因素
[J].矿床地质, 42(1): 128~156.
姚士新, 吴良士, 裴荣富. 1993. 河北邯邢地区洪山岩体地质地球化学及铜(金)矿化特征
[J]. 地质与勘探, 5(1): 11~16.
叶美芳, 刘三, 解古巍, 等. 2016. 应用扫描电镜-X射线衍射-电子探针研究北山斑岩铜矿区绢英岩中白色云母的特征
[J]. 岩矿测试, 35(2): 166~177.
尹明, 郭敏, 张海东. 2014. 太行山南段中生代杂岩体成因及其演化分析
[J]. 西北地质, 47(3): 43~53.
曾淑明, 张艳, 韩润生, 等. 2023. 滇西南翁孔坝铜多金属矿床绿泥石特征及其地质意义
[J]. 矿床地质, 42(4): 828~844.
翟明国, 樊祺诚, 张宏福, 等. 2005. 华北东部岩石圈减薄中的下地壳过程: 岩浆底侵、置换与拆沉作用
[J]. 岩石学报, 21(6): 1 509~1 526.
张波, 苏尚国, 王国栋, 等. 2020. 河北武安洪山正长岩杂岩体中单斜辉石矿物成分特征与岩浆演化过程
[J]. 中国地质, 47(3): 782~797.
张海东, 刘建朝, 陈正乐, 等. 2014. 太行山南段平顺杂岩体成因: 岩石学、年代学和地球化学证据
[J]. 大地构造与成矿学, 38(2): 454~471.
张娟, 刘新星, 王义天, 等. 2021. 陕西凤太矿集区八卦庙金矿床绿泥石特征及其找矿意义
[J]. 地质通报, 40(4): 586~603.
张展适, 华仁民, 季峻峰, 等. 2007. 20和361铀矿床中绿泥石的特征及其形成环境研究
[J]. 矿物学报, 27(2): 161~172.
赵友东, 吴俊奇, 凌洪飞, 等. 2016. 赣南富城岩体黑云母及其蚀变产物绿泥石的矿物化学研究——对铀成矿的指示意义
[J]. 矿床地质, 35(1): 153~168.
周栋, 赵太平, 赵鹏彬, 等. 2018. 豫西康山金银铅锌矿床绿泥石电子探针成分特征及其地质意义
[J]. 矿产勘查, 9(5): 803~824.
周凌, 陈斌. 2005. 南太行洪山正长岩体的成因和意义: 锆石SHRIMP年代学、化学成分和Sr-Nd同位素特征
[J]. 自然科学进展, 11(1): 1 357~1 365.

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王凯迪，张娟*，王红，刘新星，张勇，王丽杰，李若丹，关子琼，薛宇. 太行山南段洪山沟铜金矿床白云母和绿泥石特征及其找矿意义 [J]. 岩石矿物学杂志. 2025; 44; (4). 924 - 948.

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