SO2和NO2在白云母表面的非均相反应研究-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

SO₂和NO₂在白云母表面的非均相反应研究

Heterogeneous reactions of SO₂ and NO₂ on the surface of muscovite

ES评分 0 浏览量：285 下载量：0

DOI	10.20086/j.cnki.yskw.2024.0415
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2024, 43(4)
作者	张星宇，董发勤*，郑飞，霍婷婷，周琳，余洁雨，赵方源，郭铭，李文金,
作者单位	1. 西南科技大学固体废物处理与资源化教育部重点实验室, 四川绵阳 621010; 2. 西南科技大学环境与资源学院, 四川绵阳 621010; 3. 西昌学院理学院, 四川西昌 615013; 4. 西南科技大学材料与化学学院, 四川绵阳 621010
摘要	白云母是大气中矿物气溶胶的重要组分之一,研究大气中常见气体在其表面的非均相反应,在一定程度上可揭示大气环境中化学反应过程。文章采用自制石英玻璃微型反应器研究了SO₂和NO₂在白云母颗粒物表面的非均相反应,并探讨了相对湿度(RH)及光照对该反应的影响。结果表明,白云母对SO₂和NO₂均有一定的吸附活性,有紫外光和无紫外光条件下,SO₂的反应产物分别以SO^2-₄和SO^2-₃为主,NO₂的产物均以NO^-₃为主;RH或者紫外光照对反应均具有促进作用,两者对硫酸盐和硝酸盐的生成有协同效应;当SO₂和NO₂在白云母表面共存时,既有协同作用又存在竞争反应,SO^2-₄和NO^-₃的生成量分别是SO₂、NO₂单独存在的2.09倍和77%。因此,NO₂能促进硫酸盐的生成,但SO₂对硝酸盐的生成有明显抑制作用。
Abstract	Muscovite is the important component of mineral aerosols in the atmosphere. The researches for heterogeneous reactions of common gases in the atmosphere on the surface of muscovite will reveal the chemical reaction process in the atmosphere to a certain extent. In this study, the heterogeneous reaction of SO₂ and NO₂ on the surface of muscovite particles was investigated by a self-made quartz glass microreactor, and the effects of relative humidity (RH) and light on the reaction were also discussed. The results showed that muscovite has certain adsorption activity for both SO₂ and NO₂. The products in SO₂ reaction with and without ultraviolet irradiation were mainly salt compounds containing SO^2-₄ and SO^2-₃, respectively, while the products in NO₂ reaction were always mainly salt compounds containing NO^-₃. The increase of RH or ultraviolet light had a promoting effect on the reaction, and they had a synergistic effect on the formation of sulfate and nitrate. When SO₂ and NO₂ coexist on the surface of muscovite, there were both synergistic effect and competitive effect, and the generation amount of SO^2-₄ and NO^-₃ was 2.09 times and 77% of that in the presence of a single gas, respectively. Therefore, NO₂ promoted the formation of sulfate, but SO₂ had a significant inhibitory effect on the formation of nitrate.
关键词	SO₂；NO₂；白云母；非均相反应
KeyWord	SO₂; NO₂; muscovite; heterogeneous reaction
基金项目
页码	994-1004

参考文献
相关文献

Arana J, Sousa D G, Diaz O G, et al. 2019. Effect of NO₂ and NO^-₃/HNO₃ adsorption on no photocatalytic conversion
[J]. Applied Catalysis B Environmental, 244: 660~670. Baltrusaitis J, Jayaweera P M and Grassian V H. 2009. XPS study of nitrogen dioxide adsorption on metal oxide particle surfaces under different environmental conditions
[J]. Physical Chemistry Chemical Physics, 11(37): 8 295~8 305. Chu Biwu, Wang Yali, Yang Weiwei, et al. 2019. Effects of NO₂ and C₃H₆ on the heterogeneous oxidation of SO₂ on TiO₂ in the presence or absence of UV irradiation
[J]. Atmospheric Chemistry and Physics, 19(23): 14 777~14 790. Dash B, Jena S K and Rath S S. 2022. Adsorption of Cr (Ⅲ) and Cr (Ⅵ) ions on muscovite mica: Experimental and molecular modeling studies
[J]. Journal of Molecular Liquids, 357: 119116. Fu H B, Wang X, Wu H B, et al. 2007. Heterogeneous uptake and oxidation of SO₂ on iron oxides
[J]. Journal of Physical Chemistry C, 111(16): 6 077~6 085. Gen M S, Zhang R F, Huang D D, et al. 2019a. Heterogeneous oxidation of SO₂ in sulfate production during nitrate photolysis at 300 nm: Effect of pH, relative humidity, irradiation intensity, and the presence of organic compounds
[J]. Environmental Science & Technology, 53(15) : 8 757~8 766. Gen M S, Zhang R F, Huang D D, et al. 2019b. Heterogeneous SO₂ oxidation in sulfate formation by photolysis of particulate nitrate
[J]. Environmental Science & Technology Letters, 6: 89~61. Greenspan L. 1997. Humidity fixed points of binary saturated aqueous solutions
[J]. Journal of research of the National Bureau of Standards. Section A, Physics and chemistry, 81(1): 81~89. Han Lihui, Chen Yuanyuan, Jia Long, et al. 2014. Heterogeneous phase reaction of NO₂ on MgO particles
[J]. Science in China: Chemistry, 44(12): 2 004~2 012(in Chinese with English abstract). Han L H, Cheng S Y, Zhuang G S, et al. 2015. The changes and long-range transport of PM_2.5 in Beijing in the past decade
[J]. Atmospheric Environment, 110: 186~195. Han L H, Liu X H, Chen Y Y, et al. 2021. Key factors influencing the formation of sulfate aerosol on the surface of mineral aerosols: Insights from laboratory simulations and ACSM measurements
[J]. Atmospheric Environment, 253(1): 118341. Hasegawa K, Takanami T, Kawai T, et al. 2020. Effects of adsorbed water and hydrocarbon reactivity on the nitration of polycyclic aromatic hydrocarbons adsorbed on silica gel and Fe₂O₃ particles with NO₂
[J]. Atmospheric Environment, 236: 117641. Huang Z L, Zhang Z H, Kong W H, et al. 2017. Synergistic effect among Cl₂, SO₂ and NO₂ in their heterogeneous reactions on gamma-alumina
[J]. Atmospheric Environment, 166: 403~411. Jia Xiaohong, Wang Fu, Ren Yan, et al.2021. Heterogeneous reactions of SO₂, NO₂ with goethite, hematite and magnetite
[J]. Geochemistry, 50(1): 88~97(in Chinese with English abstract). Jiao Kunling, Lu Shangfa, Zhang Lianke, et al. 2016. Influencing factors of NO_x heterogeneous conversion of on the surface of kaolin
[J]. Journal of Environmental Engineering, 10(10): 5 821~5 826(in Chinese with English abstract). Jiao Kunling, Wang Xuewei, Zhang Lianke, et al. 2016. Experimental study of SO₂ heterogeneous conversion under No_x and/or NH₃ conditions on the surface of kaolin
[J]. Journal of Environmental Sciences, 36(11): 3 952~3 958(in Chinese with English abstract). Li L J, Hoffmann M R, Colussi A J, et al. 2018. Role of Nitrogen Dioxide in the Production of Sulfate during Chinese Haze-Aerosol Episodes
[J]. Environmental Science & Technology, 52(5): 2 686~2 693. Liu C, Ma Q X, Liu Y C, et al. 2012. Synergistic reaction between SO₂ and NO₂ on mineral oxides: A potential formation pathway of sulfate aerosol
[J]. Physical Chemistry Chemical Physics, 14(5): 1 668~1 676. Liu J P, Deng H F, Li S, et al. 2020. Light-enhanced heterogeneous conversion of NO₂ to HONO on solid films consisted of fluorene and fluorene/Na₂SO₄: An impact on urban and indoor atmosphere
[J]. Environmental Science &Technology, 54(18): 11 079~11 086. Ma Q X, Wang T, Liu C, et al. 2017. SO₂ initiates the efficient conversion of NO₂ to HONO on MgO surface
[J].Environmental Science &Technology, 51(7): 3 767~3 775. Orrling D, Fitzgerald E, Ivanov A, et al. 2011. Enhanced sulfate formation on ozone-exposed soot
[J]. Journal of Aerosol Science, 42(9): 615~620. Ullerstam M, Johnson M S, Vogt R, et al. 2003. DRIFTS and Knudsen cell study of the heterogeneous reactivity of SO₂ and NO₂ on mineral dust
[J]. Atmospheric Chemistry & Physics, 3(4): 2 043~2 051. Singh M and Singh L. 2016. Vibrational spectroscopic study of muscovite and biotite layered phyllosilicates
[J]. Indian Journal of Pure and Applied Physics, 54(2): 116~122. Wang H H, Zhong C, Ma Q X, et al. 2020. The adsorption and oxidation of SO₂ on MgO surface: Experimental and DFT calculation studies
[J]. Environmental Science: Nano, 7(4): 1 092~1 101. Wang T, Liu Y Y, Deng Y, et al. 2018. The influence of temperature on the heterogeneous uptake of SO₂ on hematite particles
[J]. The Science of the Total Environment, 644(10): 1 493~1 502. Yan G X, Zhang P Z, Yang J, et al. 2021. Chemical characteristics and source apportionment of PM_2.5 in a petrochemical city: Implications for primary and secondary carbonaceous component
[J]. Journal of Environmental Science, 103: 322~335. Yang Jing, Zhu Hongfei, He Jing, et al.2019. Reaction and synergistic effect of SO₂ and NO₂ on kaolinite surface
[J]. Environmental Science and Technology, 42(4): 1~5(in Chinese with English abstract). Yuan S D, Liu S S, Wang X Y, et al. 2021. Atomistic insights into heterogeneous reaction of hydrogen peroxide on mineral oxide particles
[J]. Applied Surface Science, 556: 149707. Zhang W N, Guo Z H, Zhang W P, et al. 2022. Contribution of reaction of atmospheric amine with sulfuric acid to mixing particle formation from clay mineral
[J]. Science of the Total Environment, 821: 153336. Zheng F, Dong F Q, Zhou L, et al. 2022. Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China
[J]. Atmosphere, 13(8): 1 283. 韩力慧, 陈媛媛, 贾龙, 等. 2014. NO₂在MgO颗粒物表面的非均相反应
[J].中国科学:化学, 44(12): 2 004~2 012. 贾小红, 王甫, 任燕, 等. 2021. SO₂, NO₂与针铁矿, 赤铁矿, 磁铁矿的非均相反应
[J]. 地球化学, 50(1): 88~97. 焦坤灵, 鲁尚发, 张连科, 等. 2016. NO_x在高岭土表面非均相转化的影响因素
[J].环境工程学报, 10(10): 5 821~5 826. 焦坤灵, 王雪薇, 张连科, 等. 2016. NO_x和/或NH₃气氛下SO₂在高岭土表面非均相转化的实验研究
[J]. 环境科学学报, 36(11): 3 952~3 958. 杨静, 朱洪飞, 何静, 等. 2019. SO₂和NO₂在高岭石表面的反应和协同效应
[J].环境科学与技术, 42(4): 1~5.

引用本文

张星宇，董发勤*，郑飞，霍婷婷，周琳，余洁雨，赵方源，郭铭，李文金. SO₂和NO₂在白云母表面的非均相反应研究 [J]. 岩石矿物学杂志. 2024; 43; (4). 994 - 1004.

文献评论

相关学者

相关机构