江西北武夷地区老虎洞铅锌矿床成因研究——硫化物原位微量元素及硫同位素证据-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

江西北武夷地区老虎洞铅锌矿床成因研究——硫化物原位微量元素及硫同位素证据

Genesis of the Laohudong Pb-Zn deposit in the north Wuyi area in Jiangxi Province: Evidence from in situ trace element and sulfur isotope of sulfides

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DOI	10.20086/j.cnki.yskw.2024.0412
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2024, 43(4)
作者	范诗妮，朱云，李桂贤，石得凤*，贾梦洁,
作者单位	1. 湖南科技大学地球科学与空间信息工程学院, 湖南湘潭 411201; 2. 江西省地质局第十地质大队, 江西鹰潭 335000
摘要	江西北武夷地区处于钦杭成矿带上的萍乡-广丰结合带南侧,多期构造事件和岩浆活动在该区形成了复杂的地质构造格局,铜铅锌多金属矿床成矿潜力巨大。但由于江西北武夷地区铅锌矿床普遍规模较小,研究程度不足,缺乏物质来源、成矿条件、矿床成因等问题的深入认识。本文以铅山老虎洞铅锌矿床为研究对象,通过原位主量、微量元素和硫同位素分析技术,揭示主要硫化物的主量、微量元素和硫同位素组成特征,以此探讨成矿温度、物质来源和矿床成因。EPMA测试显示闪锌矿内Fe含量(质量分数)在7.58%~8.27%之间,结合LA-ICP-MS微量元素测试结果,闪锌矿富集Fe、Mn、Cu、Cd元素,Co、Ni、Ag、In、Pb元素含量次之,Ga、Ge、As、Se、Sn、Bi元素含量相对较低。其中,Mn、Fe、Cd、In、Co主要以类质同象的形式赋存于闪锌矿中,Cu、Ag、Pb以类质同象和显微包体两种形式赋存于闪锌矿中。闪锌矿的Fe元素含量、Ga/In值(0.001~0.129)、Zn/Cd值(262~312)及相关公式计算结果均指示闪锌矿形成于中高温条件(327~337℃)。闪锌矿和黄铁矿的δ³⁴S值分别集中在2.07‰~4.16‰和0.82‰~3.19‰之间,指示矿床硫源为岩浆硫。与国内多个典型矿床相比,老虎洞铅锌矿床内闪锌矿微量元素组成与典型矽卡岩型矿床的闪锌矿相吻合。老虎洞铅锌矿床与葛仙山花岗岩杂岩体具有密切的成因联系,矿区附近黑云母花岗斑岩和二长花岗岩的成岩时代(153.9±2.7 Ma和162.8±1.2 Ma)可代表成矿时间的下限,与北武夷地区主要多金属铅锌矿床成矿时代范围一致。
Abstract	The north Wuyi area in Jiangxi Province is located on the southern side of the Pingxiang-Guangfeng junction zone on the Qinhang mineralization belt. Multiple tectonic events and magmatic activities formed a complex geological structure pattern in this area, and metallogenic potential of copper and lead-zinc polymetallic deposits is enormous. However, due to the generally small scale and insufficient research of lead-zinc deposits in the northern Wuyi area of Jiangxi Province, there is a lack of in-depth understanding of material sources, metallogenic conditions, and deposit genesis. This paper takes Laohudong Pb-Zn deposit in the northern Wuyi area of Jiangxi Prov-ince as the research object. EPMA, LA-ICP-MS and LA-MC-ICP-MS were used to reveal the major and trace element and sulfur isotope composition of sulfides, then many important information concerning the mineralization temperature, the source of metallogenic materials and the genesis of the deposit were investigated. EPMA testing shows that the Fe content in sphalerite ranges from 7.58% to 8.27%. Combined with LA-ICP-MS trace element testing, sphalerite is rich in Fe, Mn, Cu, Cd elements, followed by Co, Ni, Ag, In and Pb elements, the contents of Ga, Ge, As, Se, Sn and Bi elements are low. In sphalerite, Mn, Fe, Cd, In and Co exist in the form of isomorphism,while Cu, Ag, Pb exist in the form of isomorphism and microscopic inclusions. The content of Fe, the values of Ga/In (0.001~0.129), Zn/Cd (262~312) and calculation results of relevant formulas of sphalerite all indicated that sphalerite was formed under medium to high temperature mineralization conditions (about 327~337℃). The δ³⁴S of sphalerite and pyrite respectively concentrated between 2.07‰~4.16‰ and 0.82‰~3.19‰,they all indicated magmatic sulfur. Compared with multiple Pb-Zn deposits in China, the trace element composition of sphalerite in Laohudong Pb-Zn deposit is consistent with typical skarn deposits. The Laohudong Pb-Zn deposit has a close genetic relationship with the Gexianshan granite complex, and the age of Gexianshan granite complex (153.9±2.7 Ma and 162.8 ± 1.2 Ma) can represent the lower limit of the mineralization time, which is consistent with the range of the main polymetallic Pb-Zn deposits in the north Wuyi area.
关键词	闪锌矿；微量元素；硫同位素；原位分析；矽卡岩型矿床；老虎洞铅锌矿床；江西北武夷地区
KeyWord	sphalerite; trace elements; sulfur isotope; in situ analysis; skarn deposit; Laohudong Pb-Zn deposit; the north Wuyi area of Jiangxi Province
基金项目
页码	956-972

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相关文献

Belissont R, Boiron M C, Luais B, et al. 2014. LA-ICP-MS analyses of minor and trace elements and bulk Ge isotopes in zoned Ge-rich sphalerites from the Noailhac-Saint-Salvy deposit (France): Insights into incorporation mechanisms and ore deposition processes
[J]. Geochimica et Cosmochimica Acta, 126: 518~540. Cao Huawen, Zhang Shouting, Zheng Luo, et al. 2014. Geochemical characteristics of trace element of sphalerite in the Zhongyuku (Pb)-Zn deposit of the LuanChuan, Southwest of China
[J]. Journal of Mineralogy and Petrology, 34(3): 50~59 (in Chinese with English abstract). Chaussidon M and Lorand J P. 1990. Sulphur isotope composition of orogenic spinel lherzolite massifs from Ariege (North- Eastern Pyrenees, France): Anion microprobe study
[J]. Geochimica et Cosmochimica Acta, 54(10): 2 835~2 846. Chen Junyu, Shen Hongjie and Yan Weiyu. 2023. LA-ICP-MS trace element geochemistry of sphalerite: Metallogenic constraints on the Langyaquan Pb-Zn deposit in the Middle Tianshan metallogenic belt
[J]. Mineral Exploration, 14(3): 377~391 (in Chinese with English abstract). Chen Jie. 2016. The Petrological, Chronology and Chemical Characteristics of Mesozoic Igneous Rocks in Chenfang District the North Wuyi, and their Relationship with Mineralization
[D]. China University of Geosciences(Beijing) (in Chinese with English abstract). Ciobanu L C, Cook J N, Utsunomiya S, et al. 2015. Letter: Gold-telluride nanoparticles revealed in arsenic-free pyrite
[J]. American Mineralogist, 97(8~9): 1 515~1 518. Cook N J, Ciobanu C L, Pring A, et al. 2009. Trace and minor elements in sphalerite: A LA-ICPMS study
[J]. Geochimica et Cosmochimica Acta, 73(16): 4 761~4 791. Dai Yanpei, Yu Xinqi, Wu Ganguo, et al.2011. Characteristics of sulfide minerals genetic type and metallogenic epoch of the Caijia ping lead-zinc deposit North Wuyi Area Jiangxi Province
[J].Earth Science Frontiers, 18(2): 321~338 (in Chinese with English abstract). Dong Shuwen, Zhang Yueqiao, Long Changxing, et al. 2007. Jurassic tectonic revolution in China and new interpretation of the YanShan movement
[J]. Acta Geologica Sinica, 81(11): 1 449~1 461 (in Chinese with English abstract). Fan Hongrui, Li Xinghui, Zuo Yabin, et al. 2018. In-situ LA-(MC)-ICPMS and (Nano) SIMS trace elements and sulfur isotope analyses on sulfides and application to confine metallogenic process of ore deposit
[J]. Acta Petrologica Sinica, 34(12): 3 479~3 496 (in Chinese with English abstract). Gao Yongbao, Li Kan, Qian Bing, et al. 2016. Trace elements, S-Pb-He-Ar-C isotopes of Sphalerite in the Mayuan Pb-Zn deposit, at the northern margin of the Yangtze plate, China
[J]. Acta Petrologica Sinica, 32(1): 251~263 (in Chinese with English abstract). George L L, Cook N J and Ciobanu C L. 2016. Partitioning of trace elements in co-crystallized sphalerite-galena-chalcopyrite hydrothermal ores
[J]. Ore Geology Reviews, 77: 97~116. Gong Xuejing, Zeng Jianhui and Cao Dianhua. 2019. Sr-Nd and zircon Hf-O isotopic constraints on the petrogenesis of the ore-bearing granitic porphyry at Lengshuikeng, Jiangxi Province
[J]. Geology in China, 46(4): 818~831 (in Chinese with English abstract). Huang Anjie, Li Kangdong and Wen Zugao. 2023. Geological characteristics and SHRIMP zircon U-Pb dating of Caijiaping Pb-Zn deposit in Shangrao, Jiangxi
[J]. Journal of Guilin University of Technology, 43(2): 176~183 (in Chinese with English abstract). Keith M, Haase K M, Schwarz-Schampera U, et al. 2014. Effects of temperature, sulfur, and oxygen fugacity on the composition of sphalerite from submarine hydrothermal vents
[J]. Geology, 42(8): 699~702. Leng Chengbiao and Qi Youqiang. 2017. Genesis of the Lengshuikeng Ag-Pb-Zn orefield in Jiangxi: Constraint from in-situ LA-ICP MS analyses of minor and trace elements in sphalerite and galena
[J]. Acta Geologica Sinica, 91(10): 2 256~2 272 (in Chinese with English abstract). Li Xiaofeng, Yasushi Watanabe and Qu Wenjun. 2007. Textures and geochemical characteristics of granitic rocks in Yongping climaxtype Cu-Mo deposit, Jiangxi, southeastern China, and their alteration, mineralization and tectonic regime
[J]. Acta Petrologica Sinica, 23(10): 2 353~2 365(in Chinese with English abstract). Li Yungang and Zhu Chuanwei. 2020. The distribution signatures of major and trace elements in zoned sphalerite from lead-zinc deposits: A case study from the Huize deposit
[J]. Acta Mineralogica Sinica, 40(6): 765~771 (in Chinese with English abstract). Li Zhaoding, Quan Heng and Li Zhitong. 2003. Mesozoic and Cenozoic Igneous Rock and their Deep Processes in Eastern China
[M]. Beijing: Geology Press (in Chinese). Liu Huan, Zhang Changqing, Ji Xiaojia, et al. 2022. Differential enrichment of germanium in sphalerite from Huize lead-zinc deposit, Yunnan Province
[J]. Acta Mineralogica Sinica, 41(5): 1 057~1 072 (in Chinese with English abstract). Liu Tiegeng, Ye Lin, Zhou Jiaxi, et al. 2010. Cd primarily isomorphously replaces Fe but not Zn in Sphalerite
[J]. Acta Mineralogica Sinica, 30(2): 179~184 (in Chinese with English abstract). Liu Y S, Hu Z C, Gao S, et al. 2008. In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard
[J]. Chemical Geology, 257(1/2): 34~43. Liu Yingjun, Cao Liming, Li Zhaolin, et al. 1984. Elementary Geochemistry
[M]. Beijing: Science Press. Luo Ping. 2005. Metallogenetic Regularities and Prediction of Copper-Lead-Zinc-Silver Mineralization in the Area of Chenfang-Yongping, Yanshan County, Jiangxi Province
[D]. Wuhan: China University of Geosciences (Wuhan)(in Chinese with English abstract). Luo Ping. 2010. Research on Metallogenic Regularities and Prospecting Orientation of Copper Polymetal Mineral Resources in the northern WuYi of Jiangxi Province
[D]. Beijing:China University of Geosciences (in Chinese with English abstract). Mao Jingwen, Chen Maohong, Yuan Shunda, et al. 2011. Geological characteristics of the Qinhang (or Shihang) metallogenic belt in South China and spatia-temporal distribution regularity of mineral deposits
[J]. Acta Geologica Sinica, 85(5): 636~658 (in Chinese with English abstract). Mao Jingwen, Xie Guiqing, Guo Chunli, et al. 2008. Spatial-temporal distribution of Mesozoic ore deposits in South China and their metallogenic settings
[J]. Geological Journal of China Universities, 14(4): 510~526 (in Chinese with English abstract). Meng Xiangjin, Hou Zengqian and Dong Guangyu. 2009. Geological characteristics and mineralization timing of the Lengshuikeng porphyry Pb-Zn-Ag deposit Jiangxi Province
[J]. Acta Geologica Sinica, 83(12): 1 951~1 967 (in Chinese with English abstract). Möller P. 1987. Correlation of homogenization temperatures of accessory minerals from sphalerite-bearing deposits and Ga/Ge model temperatures
[J]. Chemical Geology, 61(1): 153~159. Ohmoto H and Rye R O. 1979. Isotopes of Sulfur and Carbon
[C]//Barnes H L. Geochemistry of Hydrothermal Ore Deposits. 2 nd Edition. New York: J. Wiley and Sons, Inc., 798. Reich M, Deditius A, Chryssoulis S, et al. 2013. Pyrite as a record of hydrothermal fluid evolution in a porphyry copper system: A SIMS/EMPA trace element study
[J]. Geochimica et Cosmochimica Acta, 104: 42~62. Ren Tao, Zhou Jiaxi, Wang Die, et al. 2019. Trace elemental and S-Pb isotopic geochemistry of the Fule Pb-Zn deposit, NE Yunnan Province
[J]. Acta Petrologica Sinica, 35(11): 3 493~3 505 (in Chinese with English abstract). Shi Defeng, Chen Dongsheng, Zhu Yun, et al. 2021. Trace element characteristics of sulfides from Dingjiashan Pb-Zn deposit in Meixian of central Fujian Province and their metallogenic significance
[J]. Acta Mineralogica Sinica, 40(3): 432~448 (in Chinese with English abstract). Shi Defeng, Li Guixian, Zhu Yun, et al. 2023. In situ trace elements of sphalerite from Yongping copper deposit in Jiangxi province: Implication for the ore genesis
[J]. Acta Mineralogica Sinica, 43(5): 653~664 (in Chinese with English abstract). Si Rongjun, Gu Xuexiang, Xiao Chun, et al. 2011. Geochemical character of trace elements in sphalerite from fule Pb-Zn deposit, Yunnan Province
[J]. Journal of Mineralogy and Petrology, 31(3): 34~40 (in Chinese with English abstract). Su Qiangwei, Mao Jingwen, Song Shiwei, et al. 2021. Zircon U-Pb ages, Hf isotope and trace element characteristics of ore-related intrusions in Yongping Cu-W deposit, Jiangxi and their geological significance
[J]. Mineral Deposits, 40(6): 1 199~1 213 (in Chinese with English abstract). Sun B K, Lü X B, Wang S G, et al. 2023. Evolution of an ancient VMS ore-forming system recorded by pyrite and sphalerite mineral texture, trace elements, and sulfur isotope: A case study from the Huangtupo Cu-Zn (-Au) deposit, Eastern Tianshan, NW China
[J]. Ore Geology Reviews, 158: 1~23. Wang Haoyu, Ye Lin, Hu Yusi, et al. 2021. Trace element characteristics in sphalerites from the Laochangping Pb-Zn deposit in the Southeastern Chongqing
[J]. Acta Mineralogica Sinica, 41(6): 623~634 (in Chinese with English abstract). Wang Junlin, Deng Anping, Zhang Yu, et al. 2020. Cu-Pb-Zn and W-Mo-Pb-Zn systematic mineralization environments of Huangshaping deposit in Hunan: Indicator of sphalerite geochemistry
[J]. Mineral Resources and Geology, 34(1): 56~63 (in Chinese with English abstract). Wen Chunqi and Duo Ji. 2009. Research Method of Deposit
[M]. Sichuan: Sichuan Science and Technology Press (in Chinese). Wen H, Zhu C, Zhang Y, et al. 2016. Zn/Cd ratios and cadmium isotope evidence for the classification of lead-zinc deposits
[J]. Scientific Reports, 6(1): 1~8. Wu Delai, Zhang Jiajing, Hua Ronghui, et al. 2008. Metallogenic geological characteristics and ore-controlling factors of Liangjia copper polymetallic Ore deposit in the northern Wuyi area
[J]. Journal of East China University of Technology,31 (3): 223~230 (in Chinese with English abstract). Wu Ganguo, Zhang Da, Peng Runmin, et al. 2004. Study on the evolution regularity of mineralization ages in south eastern china
[J]. Earth Science Frontiers, 11(1): 237~247 (in Chinese with English abstract). Xing Bo, Zheng Wei, Ouyang Zhixia, et al. 2016. Sulfide microanalysis and S isotope of Miaoshan Cu polymetallic deposit in western Guangdong Province, and its constraints on the ore genesis
[J]. Acta Geologica Sinica, 90(5): 971~986 (in Chinese with English abstract). Xu Qingsheng, Wei Yingwen, Huang Anjie, et al. 2014. Geochemical features, zircon U-Pb ages and relationship to Pb-Zn mineralization of the subvolcanic rocks in Lizikeng volcanic basin, Shangrao, Jiangxi
[J]. Geological Review, 60(4): 932~944 (in Chinese with English abstract). Yang Jinhua, Zhu Yun, Luo Pin, et al. 2019. Geological report on the reserves of Laohudong Pb-Zn deposit in Gangdong township, Qianshan County, Jiangxi Province
[R]. 223 Geological Team of Coal Geological Bureau of Jiangxi Province (in Chinese). Yang Junjie, Yang Xingke, Li Jianbo, et al. 2022. Constraints on the genesis of the Shuangwang gold deposit in Qinling Orogen, central China: Evidence from in situ trace element and sulfur isotope
[J]. Minerals, 12(8): 995. Yang Minggui and Mei Yongwen. 1997. Characteristics of geology and metallization in the Qinzhou-Hangzhou paleoplate juncture
[J]. Geology and Mineral Resources of South China, (3): 52~59 (in Chinese with English abstract). Yang Minggui, Huang Shuibao, Lou Fasheng, et al. 2009. Lithospheric structure and large-scale metallogenic process in Southeast China continental area
[J]. Geology in China, 36(3): 528~543 (in Chinese with English abstract). Ye Lin, Li Zhenli, Hu Yusi, et al. 2016. Trace elements in sulfide from the Tianbaoshan Pb-Zn deposit, Sichuan Province, China: A LA-ICPMS study
[J]. Acta Petrologica Sinica, 32(11): 3 377 ~3 393(in Chinese with English abstract). Ye Lin, Liu Yuping, Zhang Qian, et al. 2017. Trace and rare earth elements characteristics of sphalerite in Dulong super large Sn-Zn polymetallic ore deposit, Yunnan Province
[J]. Journal of Jilin University (Earth Science Edtion), 47(3): 734~750 (in Chinese with English abstract). Ye Lin, Yang Yulong and Baotan. 2012. Trace element composition of sphalerite in different genesis lead-zinc deposits—A case study of LA-ICPMS analyses
[J]. Mineral Deposits, 31(S1): 985~986 (in Chinese with English abstract). Yu Xinqi, Wu Gangue, Zhang Da, et al. 2005. Research progress of transduction about Mesozoic regime in southeast of China
[J]. Progress in Natural Science, 15(10): 1 167~1 174 (in Chinese with English abstract). Yuan B, Zhang C Q, Yu H J, et al. 2018. Element enrichment characteristics: Insights from element geochemistry of sphalerite in Daliangzi Pb-Zn deposit, Sichuan, Southwest China
[J]. Journal of Geochemical Exploration, 186: 187~201. Yuan Bo, Mao Jingwen, Yan Xinghu, et al. 2014. Sources of metallogenic materials and metallogenic mechanism of Daliangzi Ore Field in Sichuan Province: Constraints from geochemistry of S, C, H, O, Sr isotope and trace element in sphalerite
[J]. Acta Petrologica Sinica, 30(1): 209~220 (in Chinese with English abstract). Zeng Qingwen, Dai Xianglin, Dong Guochen, et al. 2023. Trace element characteristics of sphalerite in the Haobugao Zn-Pb deposit, Inner Mongolia, and their geological significance
[J]. Acta Petrologica Sinica, 39(2): 567~582 (in Chinese with English abstract). Zhang Huishan, Li Yanguang, Quan Shoucun, et al. 2018. Geochemical characteristics of metallic sulfides from the Kaladaban deposit in Xinjiang and its implications for Pb-Zn ore-forming mechanism
[J]. Acta Petrologica Sinica, 34(8): 2 295~2 311 (in Chinese with English abstract). Zhang Jiajing, Wu Musen, Chen Zhenghui, et al. 2009. Geochronologic study on the Jinzhuping molybdenum-polymetallic deposit from Shangrao of Jiangxi province
[J]. Rock and Mineral Analysis, 28(3): 228~232 (in Chinese with English abstract). Zhang Jiajing, Zhong Kunbiao, Li Bochun, et al. 2007. Metallogenic Geological Features and Pre-prospecting Potential Analysis for the Late Paleozoic Basin in Chenfang, North Wuyi
[C]// Anhui Geological Society. Strengthen the geological work to promote the harmonious development of social economy-2007 six provinces and one city in East China Geological Science and Technology Forum Papers. Hefei University of Technology Publishing House, 220~224 (in Chinese with English abstract). Zhang Jiajing, Wang Denghong and Liu Shanbao. 2012. Geochronology and isotopic compositions of the Huangbi lead-zinc deposits, Jiangxi, China
[J]. Acta Petrologica Sinica, 28(10): 3 325~3 333 (in Chinese with English abstract). Zhang Qian. 1987. Differentiation genesis of lead-zinc deposits by trace element diagrams of galena and sphalerite
[J]. Geology-Geochemistry, 9: 1~12 (in Chinese with English abstract). Zheng Y F and Hoefs J. 1993. Effects of mineral precipitation on the sulfur isotope composition of hydrothermal solutions
[J]. Chemical Geology, 105(4): 259~269. Zhu Yun and Zhou Chuang. 2022. Preliminary study on the geological characteristics and genesis of the Laohudong Pb-Zn deposit in Yanshan, Jiangxi Province
[J]. China Metal Bulletin, (11): 55~57 ( in Chinese) Zou Zhichao, Hu Ruizhong, Bi Xianwu, et al. 2012. Trace element geochemistry of the Liziping Pb-Zn deposit, the Lanping Basin, Northwest Yunnan Province, China
[J]. Geochimica, 41(5): 482~496 (in Chinese with English abstract). 曹华文, 张寿庭, 郑硌, 等. 2014. 河南栾川矿集区中鱼库(铅)锌矿床闪锌矿微量元素地球化学特征
[J]. 矿物岩石, 34(3): 50~59. 陈钧渝, 沈鸿杰, 颜伟裕. 2023. 中天山狼牙泉铅锌矿床闪锌矿LA-ICP-MS微量元素特征对矿床成因的指示意义
[J]. 矿产勘查, 14(3): 377~391. 陈杰. 2016. 北武夷陈坊地区中生代侵入岩特征与成矿
[D]. 北京: 中国地质大学(北京). 代堰锫, 余心起, 吴淦国, 等. 2011. 北武夷蔡家坪铅锌矿床硫化物特征、矿床成因类型及成矿时代
[J]. 地学前缘, 18(2): 321~338. 董树文, 张岳桥, 龙长兴, 等. 2007. 中国侏罗纪构造变革与燕山运动新诠释
[J]. 地质学报, 81(11): 1 449~1 461. 范宏瑞, 李兴辉, 左亚彬, 等. 2018. LA-(MC)-ICPMS和(Nano)SIMS硫化物微量元素和硫同位素原位分析与矿床形成的精细过程
[J]. 岩石学报, 34(12): 3 479~3 496. 高永宝, 李侃, 钱兵, 等. 2016. 扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究
[J]. 岩石学报, 32(1): 251~263. 龚雪婧, 曾建辉, 曹殿华. 2019. 江西冷水坑矿床含矿花岗斑岩的Sr-Nd及锆石Hf-O同位素研究
[J]. 中国地质, 46(4): 818~831. 黄安杰, 李康东, 温祖高. 2023. 江西上饶蔡家坪铅锌矿床地质特征和成矿岩体SHRIMP锆石U-P定年
[J]. 桂林理工大学学报, 43(2): 176~183. 冷成彪, 齐有强. 2017. 闪锌矿与方铅矿的LA-ICP MS微量元素地球化学对江西冷水坑银铅锌矿田的成因制约
[J]. 地质学报, 91(10): 2 256~2 272. 李晓峰, Yasushi Watanabe, 屈文俊. 2007. 江西永平铜矿花岗质岩石的岩石结构、地球化学特征及其成矿意义
[J]. 岩石学报, 23: 2 353~2 365. 李云刚, 朱传威. 2020. 会泽铅锌矿床环带状闪锌矿中主微量元素分布特征及其意义
[J]. 矿物学报, 40(6): 765~771. 李兆鼐, 权恒, 李之彤. 2003. 中国东部中新生代火成岩及其深部过程
[M]. 北京: 地质出版社. 刘欢, 张长青, 吉晓佳, 等. 2022. 云南会泽铅锌矿床闪锌矿中稀散元素锗的差异性富集规律研究
[J]. 矿床地质, 41(5): 1 057~1 072. 刘铁庚, 叶霖, 周家喜, 等. 2010. 闪锌矿中的Cd主要类质同象置换Fe而不是Zn
[J]. 矿物学报, 30(2): 179~184. 刘英俊, 曹励明, 李兆麟, 等. 1984. 元素地球化学
[M]. 北京: 科学出版社, 242~415. 罗平. 2005. 江西铅山县陈坊-永平地区铜铅锌银成矿规律与成矿预测
[D]. 武汉: 中国地质大学(武汉). 罗平. 2010. 江西北武夷地区铜多金属矿成矿规律及找矿方向研究
[D]. 北京: 中国地质大学(北京). 毛景文, 陈懋弘, 袁顺达, 等. 2011. 华南地区钦杭成矿带地质特征和矿床时空分布规律
[J]. 地质学报, 85(5): 636~658. 毛景文, 谢桂青, 郭春丽, 等. 2008. 华南地区中生代主要金属矿床时空分布规律和成矿环境
[J]. 高校地质学报, 14(4): 510~526. 孟祥金, 侯增谦, 董光裕, 等. 2009. 江西冷水坑斑岩型铅锌银矿床地质特征热液蚀变与成矿时限
[J]. 地质学报, 83(12): 1 951~1 967. 任涛, 周家喜, 王蝶, 等. 2019. 滇东北富乐铅锌矿床微量元素和S-Pb同位素地球化学研究
[J]. 岩石学报, 35(11): 3 493~3 505. 石得凤, 陈冬生, 朱云, 等. 2021. 闽中梅仙丁家山铅锌矿床硫化物微量元素地球化学特征及其成矿意义
[J]. 矿床地质, 40(3): 432~448. 石得凤, 李桂贤, 朱云, 等. 2023. 江西永平铜矿闪锌矿原位微量元素特征与矿床成因
[J]. 矿物学报, 43(5): 653~664. 司荣军, 顾雪祥, 肖淳, 等. 2011. 云南省富乐铅锌矿床闪锌矿中微量元素地球化学特征——兼论深色闪锌矿富集Cd的原因
[J]. 矿物岩石, 31(3): 34~40. 苏蔷薇, 毛景文, 宋世伟, 等. 2021. 江西永平Cu-W矿床成矿岩体的锆石U-Pb年龄、Hf同位素、微量元素特征及其意义
[J]. 矿床地质, 40(6): 1 199~1 213. 王皓宇, 叶霖, 胡宇思, 等. 2021. 渝东南老厂坪铅锌矿床闪锌矿微量元素组成特征
[J]. 矿物学报, 41(6): 623~634. 王俊霖, 邓安平, 张宇, 等. 2020. 湖南黄沙坪多金属矿床闪锌矿对Cu-Pb-Zn和W-Mo-Pb-Zn成矿系统环境的指示
[J]. 矿产与地质, 34(1): 56~63. 温春齐, 多吉. 2009. 矿床研究方法
[M]. 四川: 四川科学技术出版社, 1~230. 吴德来, 张家菁, 华荣辉, 等. 2008. 北武夷梁家铜多金属矿成矿地质特征及控矿因素
[J]. 东华理工大学学报(自然科学版), 31(3): 223~230. 吴淦国, 张达, 彭润民, 等. 2004. 东南沿海成矿带矿床形成的时间演化规律研究
[J]. 地学前缘, 11(1): 237~247. 邢波, 郑伟, 欧阳志侠, 等. 2016. 粤西庙山铜多金属矿床硫化物原位微区分析及S同位素对矿床成因的制约
[J]. 地质学报, 90(5): 971~986. 徐庆胜, 魏英文, 黄安杰, 等. 2014. 江西上饶梨子坑火山盆地潜火山岩地球化学特征、锆石U-Pb年龄及其与铅锌矿成矿关系
[J]. 地质论评, 60(4): 932~944. 杨金华, 朱云, 罗萍, 等. 2019. 江西省铅山县港东乡老虎矿区铅锌矿储量地质报告
[R]. 江西省煤田地质局二二三地质队. 杨明桂, 梅勇文. 1997. 钦-杭古板块结合带与成矿带的主要特征
[J]. 华南地质与矿产, (3): 52~59. 杨明桂, 黄水保, 楼法生, 等. 2009. 中国东南陆区的岩石圈结构与大规模成矿作用
[J]. 中国地质, 36(3): 528~543. 叶霖, 李珍立, 胡宇思, 等. 2016. 四川天宝山铅锌矿床硫化物微量元素组成: LA-ICPMS研究
[J]. 岩石学报, 32(11): 3 377~3 393. 叶霖, 刘玉平, 张乾, 等. 2017. 云南都龙超大型锡锌多金属矿床中闪锌矿微量及稀土元素地球化学特征
[J]. 吉林大学学报(地球科学版), 47(3): 734~750. 叶霖, 杨玉龙, 鲍谈. 2012. 不同类型铅锌矿床中闪锌矿微量元素组成特征——以LA-ICP MS分析测试为例
[J]. 矿床地质, 31(S1): 985~986. 余心起, 吴淦国, 张达, 等. 2005. 中国东南部中生代构造体制转换作用研究进展
[J]. 自然科学进展, 15(10): 1 167~1 174. 袁波, 毛景文, 闫兴虎, 等. 2014. 四川大梁子铅锌矿成矿物质来源与成矿机制: 硫、碳、氢、氧、锶同位素及闪锌矿微量元素制约
[J]. 岩石学报, 30(1): 209~220. 曾庆文, 戴香麟, 董国臣, 等. 2023. 内蒙古浩布高铅锌矿床闪锌矿微量元素特征及其地质意义
[J]. 岩石学报, 39(2): 567~582. 张辉善, 李艳广, 全守村, 等. 2018. 阿尔金喀腊达坂铅锌矿床金属硫化物元素地球化学特征及其对成矿作用的制约
[J]. 岩石学报, 34(8): 2 295~2 311. 张家菁, 吴木森, 陈郑辉, 等. 2009. 江西省上饶县金竹坪钼多金属矿床成矿年代学研究
[J]. 岩矿测试, 28(3): 228~232. 张家菁, 钟坤彪, 李伯春, 等. 2007. 北武夷陈坊晚古生代盆地成矿地质特征及找矿潜力分析
[C]//安徽省地质学会. 加强地质工作促进社会经济和谐发展——2007年华东六省一市地学科技论坛论文集. 合肥工业大学出版社, 220~224. 张家菁, 王登红, 刘善宝, 等. 2012. 江西省铅山县篁碧铅锌矿区同位素年代学和稳定同位素组成
[J]. 岩石学报, 28(10): 3 325~3 333. 张乾. 1987. 利用方铅矿、闪锌矿的微量元素图解法区分铅锌矿床的成因类型
[J]. 地质地球化学, 9: 1~12. 朱云, 周楚昂. 2022. 江西铅山老虎洞铅锌矿床地质特征及成因初探
[J]. 中国金属通报, (11): 55~57. 邹志超, 胡瑞忠, 毕献武, 等. 2012. 滇西北兰坪盆地李子坪铅锌矿床微量元素地球化学特征
[J]. 地球化学, 41(5): 482~496.

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范诗妮，朱云，李桂贤，石得凤*，贾梦洁. 江西北武夷地区老虎洞铅锌矿床成因研究——硫化物原位微量元素及硫同位素证据 [J]. 岩石矿物学杂志. 2024; 43; (4). 956 - 972.

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