缅甸紫色翡翠的致色机理——光谱和色度学研究-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

缅甸紫色翡翠的致色机理——光谱和色度学研究

Colouration in purple jadeite-jade from Myanmar: A spectroscopy and chromaticity investigation

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DOI	10.20086/j.cnki.yskw.2024.0312
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2024, 43(3)
作者	商嫣然，王伟钊，金天力，黄琳铭，吴中允，郭颖*,
作者单位	中国地质大学(北京) 珠宝学院, 北京 100083
摘要	采用电子探针分析、能量色散X射线荧光光谱、傅里叶变换红外光谱、紫外-可见光谱和色度学方法等多种手段,对55个缅甸紫色翡翠样品进行了全面分析。结果表明,缅甸紫色翡翠的主要化学成分为SiO₂、Al₂O₃和Na₂O,含量与标准硬玉接近。色度学测试分析显示,缅甸紫色翡翠的彩度C^主要受色度值a^控制,而色调角h°主要由色度值b^*控制。缅甸紫色翡翠可分为两种类型:Ⅰ型紫色翡翠主要由Mn³⁺致色,并在紫外-可见-近红外光谱570 nm显示主要吸收带;Ⅱ型紫色翡翠由于Fe²⁺-Ti⁴⁺之间的电荷转移致色,在光谱540 nm和610 nm显示吸收。两种翡翠中均存在Fe³⁺的吸收峰,样品中的全铁含量决定其色调角及明度。
Abstract	55 Myanmar purple jadeite-jades samples were comprehensively analyzed by electron microprobe analysis (EMPA), energy-dispersive X-ray fluorescence (ED-XRF) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-VIS) spectroscopy and colorimetric methods. The results show that the main chemical compositions of Myanmar purple jadeite-jades are SiO₂, Al₂O₃ and Na₂O, and the contents are close to those of standard jadeite. Chromaticity test analysis showed that the chroma C^* of purple jadeite-jade is mainly controlled by the colour coordinate a^, while the hue h° is mainly controlled by the colour coordinate b^. Myanmar purple jadeite-jades can be classified into two types: Type Ⅰ show the main absorption bands at 570 nm which is assigned by chromophore Mn³⁺ and Type Ⅱ with two main absorptions at 540 nm and 610 nm are colored by charge transfer between Fe²⁺-Ti⁴⁺. The absorption peaks of Fe³⁺ existed in both types of Myanmar purple jadeite-jades, and the full iron content in the samples determined their hue and lightness.
关键词	缅甸紫色翡翠；颜色成因；光谱学；宝石色度学
KeyWord	Myanmar purple jadeite-jade; colouration; spectroscopy; gemmology colourimetry
基金项目
页码	643-651

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商嫣然，王伟钊，金天力，黄琳铭，吴中允，郭颖*. 缅甸紫色翡翠的致色机理——光谱和色度学研究 [J]. 岩石矿物学杂志. 2024; 43; (3). 643 - 651.

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