秘鲁粉色蛋白石的物相组成及颜色成因-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

秘鲁粉色蛋白石的物相组成及颜色成因

Phase composition and color origin of Peru's pink opals

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DOI	10.20086/j.cnki.yskw.2024.0301
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2024, 43(3)
作者	钱雪雯，李净净，杨丽，徐娅芬,
作者单位	1. 上海建桥学院珠宝学院, 上海 201316; 2. 国家首饰质量检验检测中心深圳实验室, 广东深圳 518020
摘要	采用X射线粉晶衍射、红外光谱仪、电子探针、激光剥蚀电感耦合等离子体质谱仪以及紫外可见光分光光度计对不同深浅的秘鲁产粉色蛋白石样品进行了物相组成及颜色成因的测试和分析。结果显示,粉色蛋白石的主要矿物组成为Opal-CT、坡缕石、石英和水,且水的类型较为丰富,包含了结晶水、结构水和沸石水。结合X射线粉晶衍射、红外光谱及电子探针分析认为粉色蛋白石的颜色与坡缕石有关,且通过XRD定量分析坡缕石的含量,认为其与颜色呈正相关。综合紫外-可见光光谱、电子探针和激光剥蚀电感耦合等离子体质谱结果分析,粉色蛋白石的颜色与坡缕石结构中的有机物醌和β类胡萝卜素及Mn²⁺有关,且Mn²⁺含量越多,颜色越深,同时提出了Fe³⁺对颜色的影响,发现Fe³⁺只出现在了深色样品中。
Abstract	X-ray powder diffraction, infrared spectroscopy, electron microprobe, laser ablation inductively coupled plasma mass spectrometry and ultraviolet-visible spectrophotometer were used to test and analyze the phase composition and color genesis of different shades of pink opal samples from Peru. The results show that the main mineral composition of pink opal is Opal-CT, palygorskite, quartz and water, and the type of water is rich, including crystal water, structural water and zeolite water. Combined with X-ray powder diffraction, electron microprobeand infrared spectrum analysis, it is considered that the color of pink opal is related to palygorskite, and the content of palygorskite was quantitatively analyzed by XRD, which was positively correlated with color. UV-visible spectrophotometer combined with electron microprobe and laser ablation inductively coupled plasma mass spectrometry showed that the color of pink opal was related to the organic quinones, β-carotene and Mn²⁺, and the more the content of Mn²⁺, the darker the color. At the same time, the effect of Fe³⁺ on color was proposed, and it was found that Fe³⁺ only appeared in dark samples.
关键词	物相组成；粉色蛋白石；秘鲁；颜色成因
KeyWord	phase composition; pink opal; Peru; color genesis
基金项目
页码	495-502

参考文献
相关文献

Amthauer G and Rossman G R. 1984. Mixed valence of iron in minerals with cation clusters
[J]. Physics and Chemistry of Minerals, 111(1): 37~51. Cámara F, Garvie L A J, Devouard B, et al. 2002. The structure of Mn-rich tuperssuatsiaite: A palygorskite-related mineral
[J]. American Mineralogist, 87(10): 1 458~1 463. Caucia F, Marinoni L, Leone A, et al. 2013a. Investigation on the gemological, physical and compositional properties of some opals from Slovakia ("Hungarian" opals)
[J]. Periodico di Mineralogia, 82(2): 251~261. Caucia F, Marinoni L and Leone A. 2013b. Physical, geochemical and gemological properties of opals from Faroe Islands
[J]. Neues Jahrbuch fur Mineralogie-Abhandlungen, 191(1): 33~43. Caucia F, Marinoni L, Leone A, et al. 2015. New physical, geochemical and gemological data of opals from Acari Mine (Arequipa Department, Peru)
[J]. Neues Jahrbuch für Mineralogie-Abhandlungen, 192(1): 73~84. Chen Hesheng, Sun Zhenya and Shao Jingchang. 2011. Investigation on FT-IR Spectroscopy for Eight Different Sources of SiO₂
[J]. Bulletin of the Chinese Ceramic Society, 30(4): 934~937(in Chinese with English abstract). Chen Tianhu. 2003. Nanometer Scale Mineralogy and Geochemistry of Palygorskite Clays in the Border of Jiangsu and Anhui Provinces
[D]. Hefei: Hefei University of Technology(in Chinese). Elzea J M, Odom I E and Miles W J. 1994. Distinguishing well ordered opal-CT and opal-C from high temperature cristobalite by X-ray diffraction
[J]. Analytica Chimica Acta, 286(1): 107~116. Elzea J M and Rice S B. 1996. TEM and X-ray diffraction evidence for cristobalite and tridymite stacking sequences in opal
[J]. Clays and Clay Minerals, 44(4): 492~500. Fammer V C. 1982. Infrared Spectra of Minerals
[M]. Ying Yupu, Wang Shousong, Li Chungeng, et al. Beijing: Science Press, 289~303(in Chinese). Fritsch E, Gaillou E, Ostroumov M, et al. 2004. Relationship between nanostructure and optical absorption in fibrous pink opals from Mexico and Peru
[J]. European Journal of Mineralogy, 16(5): 743~752. Gaillou E, Delaunay A, Rondeau B, et al. 2008. The geochemistry of gem opals as evidence of their origin
[J]. Ore Geology Reviews, 34(1~2): 113~126. Hawthorne F C, Abdu Y A, Tait K T, et al. 2013. The crystal structure of yofortierite
[J]. The Canadian Mineralogist, 51(2): 243~251. Jones J B and Segnit E R. 1971. The nature of opal I. Nomenclature and constituent phases
[J]. Journal of the Geological Society of Australia, 18(1): 57~68. Lang Xiaobo, Mao Jian, Liu Xueliang, et al. 2014. Study of spectroscopical characteristics and coloring factor of lavender jadeite
[J]. Laser & Optoelectronics Progress, 51(6): 193~197(in Chinese with English abstract). Li Suzhen, Li Zhen, Huang Yanjun, et al. 2007. Mössbauer study of occupation of iron ions in palygorskite
[J]. Nuclare Techniques, 30(4): 302~305(in Chinese with English abstract). Liu Xueliang, Fan Jianliang and Guo Shouguo. 2011. Spectroscopical characteristics and color-causing mechanismof light pink-red jadetite
[J]. Laser & Optoelectronics Progress, 48(9): 144~148 (in Chinese with English abstract). Louis M, Guillemin C J, Goni J C, et al. 1968. Coloration rose-carmin d'une sépiolite Eocène, la quincyte, par des pigments organiques
[J]. Advances in Organic Geochemistry, 31: 553~566. Machatová Z, Barbieriková Z, Poliak P, et al. 2016. Study of natural anthraquinone colorants by EPR and UV/vis spectroscopy
[J]. Dyes and pigments, 132(4): 79~93. McOrist G and Smallwood A. 1995. Trace elements in coloured opals using neutron activation analysis
[J]. Journal of Radioanalytical and Nuclear Chemistry, 198(2): 499~510. Qiao Xianrong. 2016. UV-VIS spectral analysis of lawsone in henna powder
[J]. China Surfactant Detergent ＆ Cosmetics, 46(3): 178~182(in Chinese with English abstract). Scott K J. 2001. Detection and measurement of carotenoids by UV/VIS spectrophotometry
[J]. Current Protocols in Food Analytical Chemistry, (1): F2.2.1~F2.2.10. Song Gongbao, Liu Fusheng, Cao Yongge, et al. 1999. Infrared spectrum study of palygorskite
[J]. Acta Petrologica Sinica, 15(3): 469~474(in Chinese with English abstract). Wang Haibin. 2004. UV-VIS characteristics of carotenoids and its utiliza in structural identification
[J]. Journal of Wuhan Polytechnic University, 23(4): 10~13(in Chinese with English abstract). Wu Jinlin, Ma Hong and Li Huihuang. 2022. Mineral composition and nomenclature suggestion of a type of pink opal
[J]. China Gems & Jades, (6): 15~23(in Chinese with English abstract). Xing Yingying and Qi Lijian. 2019. Thermal variation of "water" in pink opals
[J]. Laser & Optoelectronics Progress, 56(2): 244~250(in Chinese with English abstract). Yan Wenchang, Yuan Peng, Tan Daoyong, et al. 2013. Infrared spectroscopic of Mg-rich and Mg-poor palygorskite
[J]. Journal of the Chinese Ceramic Society, 41(1): 89~95 (in Chinese with English abstract). Zhang Shangqi and Lu Qi. 2017. Gemological characteristics and coloration of pink opal from Peru
[C]//Proceedings of the China International Jewelry and Jewelry Academic Conference. Beijing: China University of Geosciences, 107~112 (in Chinese). Zhong Yuanyuan. 2021. Study on the Spectroscopy Characteristics of "Taishan Biyu" and the Influencing Factors of Color and Transparency
[D]. Beijing: China University of Geosciences(in Chinese). 陈和生, 孙振亚, 邵景昌. 2011. 八种不同来源二氧化硅的红外光谱特征研究
[J]. 硅酸盐通报, 30(04): 934~937. 陈天虎. 2003. 苏皖凹凸棒石黏土纳米尺度矿物学及地球化学
[D]. 合肥: 合肥工业大学. 法默 V C. 1982. 矿物的红外光谱
[M]. 应育浦, 汪寿松, 李春庚, 等译. 北京: 科学出版社, 289~303. 郎小波, 毛荐, 刘学良, 等. 2014. 紫色翡翠的谱学特征及颜色成因探讨
[J]. 激光与光电子学进展, 51(6): 193~197. 厉淑贞, 李真, 黄彦君, 等. 2007. 穆斯堡尔谱研究坡缕石中铁的占位
[J]. 核技术, 30(4): 302~305. 刘学良, 范建良, 郭守国. 2011. 浅粉红色翡翠的谱学特征及颜色成因分析
[J]. 激光与光电子学展, 48(9): 144~148. 乔仙蓉. 2016. 紫外可见光谱分析海娜粉中的指甲花醌
[J]. 日用化学工业, 46(3): 178~182. 宋功保, 刘福生, 曹永革, 等. 1999. 坡缕石的红外光谱研究
[J]. 岩石学报, 15(3): 469~474. 王海滨. 2004. 类胡萝卜素的紫外可见光谱特性及其应用
[J]. 武汉工业学院学报, 23(4): 10~13. 吴金林, 马泓, 黎辉煌. 2022. 一种粉色蛋白石的矿物组成及其命名建议
[J]. 中国宝玉石, (6): 15~23. 邢莹莹, 亓利剑. 2019. 粉色蛋白石中"水"的热变异行为研究
[J]. 激光与光电子学进展, 56(2): 244~250. 颜文昌, 袁鹏, 谭道永, 等. 2013. 富镁与贫镁坡缕石的红外光谱
[J]. 硅酸盐学报, 41(1): 89~95. 张尚琦, 卢琪. 2017. 秘鲁粉色蛋白石的宝石学特征及其颜色成因研究
[C] //中国国际珠宝首饰学术交流会论文集. 北京: 中国地质大学, 107~112. 钟媛媛. 2021. "泰山碧玉"的谱学特征及其颜色、透明度的影响因素研究
[D]. 北京: 中国地质大学(北京).

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钱雪雯，李净净，杨丽，徐娅芬. 秘鲁粉色蛋白石的物相组成及颜色成因 [J]. 岩石矿物学杂志. 2024; 43; (3). 495 - 502.

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