海南岛玄武岩石粉废渣制备连续纤维实验研究-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

海南岛玄武岩石粉废渣制备连续纤维实验研究

An experimental study on the preparation of continuous fiber from basalt waste powder in Hainan Island

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DOI	10.20086/j.cnki.yskw.2023.0504
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2023, 42(5)
作者	李珎，徐冠立*，官军，殷诗勤，刘荣，王梦潇，胡阳,
作者单位	1. 海南省海洋地质资源与环境重点实验室, 海南海口 570206; 2. 成都理工大学地球科学学院, 四川成都 610059; 3. 海南省地质调查院, 海南海口 570206; 4. 四川省地质矿产勘查开发局一〇六地质队, 四川成都 610081
摘要	玄武岩石粉废渣是玄武岩石材破碎加工过程中产生的废料,其粒度细、销路差,尚无成熟的大规模综合利用方法。本文采集海南岛不同地区的8组玄武岩石粉废渣,利用电感耦合等离子体发射光谱仪(ICP-OES)和X射线衍射仪(XRD)分析其化学成分和矿物组分,通过差示扫描量热仪(DSC)、能谱仪(EDS)及熔融实验分析其结晶性能,筛选出最符合玄武岩纤维原料特征的样品进行纤维制备研究。通过扫描电子显微镜(SEM)及XRD分析纤维表面形貌与结晶晶相,将其性能与标准纤维进行对比。结果表明,1 450℃时制得的纤维频繁断丝,表面结晶出大量树枝状及针状的硅灰石、石英、黄长石和磁铁矿;升温至1 480℃并保温1 h后成功制得的连续纤维,仍含有黄长石和磁铁矿,断裂强力略低于标准纤维。研究结果表明利用海南岛玄武岩石粉废渣制备连续纤维具有一定可行性,本研究为海南岛玄武岩石粉废渣的处理提供了导向性建议和理论基础。
Abstract	The basalt waste powder is a by-product of the crushing and processing of basalt stone. It has a fine grain size and is difficult to sell, and there is currently no widely adopted method for comprehensive utilization on a large scale. In this study, eight groups of basalt waste powder from different areas of Hainan Island were selected for analysis. The chemical and mineral composition of the basalt waste powder was determined by inductively coupled plasma emission spectrometer (ICP-OES) and X-ray diffractometer (XRD). The crystallization properties of the basalt waste powder were analyzed by differential scanning calorimeter (DSC), energy dispersive spectroscopy (EDS), and melting experiments. The surface morphology and crystal phase of the fibers prepared from the basalt waste powder were examined by scanning electron microscope (SEM) and XRD, and their properties were compared to those of standard fibers. The results revealed that the fiber prepared at a temperature of 1 450℃ tended to break frequently, and there was a significant presence of dendritic and acicular crystals on the fiber surface. These crystals were identified as wollastonite, quartz, melilite, and magnetite. After raising the temperature to 1 480℃ and maintaining it for 1 hour, continuous fiber was successfully obtained. However, the breaking strength of the fiber was slightly lower than that of standard fibers. Melilite and magnetite were also detected in the fiber. These results validate the feasibility of preparing continuous fiber from basalt waste powder from Hainan Island. This study offers practical guidance and a theoretical foundation for the treatment of basalt waste powder on Hainan Island.
关键词	玄武岩石粉废渣；玄武岩纤维；拉丝实验；海南岛；结晶；固废利用
KeyWord	basalt waste powder; basalt fiber; wire drawing test; Hainan Island; crystallization; soild waste utilization
基金项目
页码	663-672

参考文献
相关文献

Chen Xingfen. 2018. Study on the High Strength and Performance of Continuous Basalt Fiber
[D]. Nanjing: Southeast University(in Chinese with English abstract). Fan Qicheng, Sun Qian, Li Ni, et al. 2004. Periods of volcanic activity and magma evolution of Holocene in North Hainan Island
[J]. Acta Petrologica Sinica, 20(3): 533~544(in Chinese with English abstract). Gao Y Q, Jia C, Meng L, et al. 2017. Heat resistance study of basalt fiber material via mechanical tests
[J]. IOP Conference Series: Materials Science and, Engineering, 283(1): 012016 (7pp). Geng Tie, Sheng Jie, Wei Chuanle, et al. 2017. Research on crystallization temperature of glass and its overview
[J]. Bulletin of the Chinese Ceramic Society, 36(11): 3 672~3 675(in Chinese with English abstract). Huang Zhenguo, Cai Fuxiang, Han Zhongyuan, et al. 1993. Quaternary Volcano of Hainan Island and Leizhou Peninsula
[M]. Beijing: Science Press, 1~7(in Chinese with English abstract). Huo Yonglin. 2022. Study on Crystallization Properties of Basalt Glass
[D]. Mianyang: Southwest University of Science and Technology(in Chinese with English abstract). Huo Yonglin, Huo Jichuan, Zhang Xingquan, et al. 2022. Development and utilization of basalt
[J]. Materials Reports, 36(6): 113~123(in Chinese with English abstract). Li Sunxiong, Yun Ping, Lin Yihua, et al. 2017. Regional Geology of China-Hainan Province
[M]. Beijing: Geological Publishing House, 487~496(in Chinese with English abstract). Li Y, Chu F L, Tuo W Y, et al. 2021. Review of research on basalt fibers and basalt fiber-reinforced composites in China (Ⅰ): Physicochemical and mechanical properties
[J]. Polymers and Polymer Composites, 29(9): 1 612~1 624. Liu Changjiang, Tong Xiaocong, Liu Zhong, et al. 2020. Analysis of basalt fiber raw material characteristics
[J]. Bulletin of the Chinese Ceramic Society, 39(12): 3 858~3 865(in Chinese with English abstract). Liu Jianqiang and Ren Zhongyuan. 2013. Diversity of source lithology and its identification for basalts: A case study of the Hainan basalts
[J]. Geotectonica et Metallogenia, 37(3): 471~488 (in Chinese with English abstract). Liu Zhong. 2022. Effect of Raw Material Pretreatment on Basalt Fiber Formation and Properties
[D]. Shijiazhuang: Hebei GEO University(in Chinese with English abstract). Mei Shengwang. 2018. The Petrogenesis and Geodynamic Mechanism of Late Cenozoic Basalts in North Hainan Island
[D]. Guangzhou: Guangzhou Institute of Geochemisty, Chinese Academy of Science(in Chinese with English abstract). Meng Y, Liu J X, Xia Y, et al. 2021. Preparation and characterization of continuous basalt fibre with high tensile strength
[J]. Ceramics International, 47: 12 410~12 415. Novotná M and Chen Yuwei. 2016. Comparison properties of selected inorganic fibers
[J]. Melliand China, 44(2): 14~16(in Chinese with English abstract). Song Ping, Gao Huan, Wang Ling, et al. 2022. Basic characteristics and application prospect analysis of basalt fiber
[J]. Conservation and Utilization of Mineral Resources, 42(4): 173~178 (in Chinese with English abstract). Wang X C, Li Z X, Li X H, et al. 2012. Temperature, pressure, and composition of the mantle source region of Late Cenozoic basalts in Hainan Island, SE Asia: A consequence of a young thermal mantle plume close to subduction zones?
[J]. Journal of Petrology, 53(1): 177~233. Wang Yici, Yu Wenwu, Zhang Jianliang, et al. 2014. Crystallization kinetics and microstructure of glass-ceramics prepared from Baotou steel blast furnace slag
[J]. Transactions of Materials and Heat Treatment, 35(1): 88~93(in Chinese with English abstract). Wang Yiting, Bai Zhimin, Yu Sibin, et al. 2020. Effect of mineral composition and structural of basalt on preparation process and properties of basalt fibers
[J]. China Non-Metallic Minerals Industry, (1): 23~29(in Chinese with English abstract). Wei Bin. 2011. Study on the Coating Modification of Basalt Fibers and their Chemical Stability Performance
[D]. Harbin: Harbin Institute of Technology(in Chinese with English abstract). Xing D, Xi X Y and Ma P C. 2019. Factors governing the tensile strength of basalt fibre
[J]. Composites Part A: Applied Science and Manufacturing, 119: 127~133. Yang Juan, Du Yongguo, Li Xiaodong, et al. 2007. The influence factors of the crystal separating of MgO-Al₂O₃-SiO₂ glass ceramics
[J]. Journal of Materials Engineering, (10): 42~44(in Chinese with English abstract). Yang Qiuhong and Jiang Zhonghong. 1994. The study of criterion for glass crystallization kinetics
[J]. Journal of the Chinese Ceramic Society, 22(5): 419~426(in Chinese with English abstract). 附中文参考文献陈兴芬. 2018. 连续玄武岩纤维的高强度化研究
[D]. 南京: 东南大学. 樊祺诚, 孙谦, 李霓, 等. 2004. 琼北火山活动分期与全新世岩浆演化
[J]. 岩石学报, 20(3): 533~544. 耿铁, 盛洁, 蔚川乐, 等. 2017. 玻璃结晶温度及其研究概述
[J]. 硅酸盐通报, 36(11): 3 672~3 675. 黄镇国, 蔡福祥, 韩中元, 等. 1993. 雷琼第四纪火山
[M]. 北京: 科学出版社, 1~7. 霍泳霖. 2022. 玄武岩玻璃结晶性能的研究
[D]. 绵阳: 西南科技大学. 霍泳霖, 霍冀川, 张行泉, 等. 2022. 玄武岩的开发利用进展
[J]. 材料导报, 36(6): 113~123. 李孙雄, 云平, 林义华, 等. 2017. 中国区域地质志——海南志
[M]. 北京: 地质出版社, 487~496. 刘忠. 2022. 原料预处理对玄武岩成纤及纤维性能的影响
[D]. 广州: 中国科学院广州地球化学研究所. 刘昶江, 仝晓聪, 刘忠, 等. 2020. 玄武岩纤维原料特征分析
[J]. 硅酸盐通报, 39(12): 3 858~3 865. 刘建强, 任钟元. 2013. 玄武岩源区母岩的多样性和识别特征——以海南岛玄武岩为例
[J]. 大地构造与成矿学, 37(3): 471~488. 梅盛旺. 2018. 海南岛北部晚新生代玄武岩岩石学成因及其地球动力学机制
[D]. 石家庄: 河北地质大学. Novotná M, 陈玉伟. 2016. 几种无机纤维的性能对比
[J]. 国际纺织导报, 44(2): 14~16. OSNOS S P, 李中郢, 张德福. 2005. 用玄武岩矿石制造连续纤维的方法
[P]. 广东省: CN1566005A. 宋平, 高欢, 汪灵, 等. 2022. 玄武岩纤维基本特征及应用前景分析
[J]. 矿产保护与利用, 42(4): 173~178. 王艺慈, 于文武, 张建良, 等. 2014. 包钢高炉渣微晶玻璃的结晶动力学及显微结构分析
[J]. 材料热处理学报, 35(1): 88~93. 汪溢汀, 白志民, 余思彬, 等. 2020. 原料物相和组构对玄武岩纤维制备工艺与性能的影响
[J]. 中国非金属矿工业导刊, (1): 23~29. 魏斌. 2011. 玄武岩纤维的化学稳定性能及其涂层改性研究
[D]. 哈尔滨: 哈尔滨工业大学. 杨娟, 堵永国, 李效东, 等. 2007. MgO-Al₂O₃-SiO₂微晶玻璃结晶影响因素
[J]. 材料工程, (10): 42~44. 杨秋红, 姜中宏. 1994. 玻璃结晶动力学判据研究
[J]. 硅酸盐学报, 22(5): 419~426.

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李珎，徐冠立*，官军，殷诗勤，刘荣，王梦潇，胡阳. 海南岛玄武岩石粉废渣制备连续纤维实验研究 [J]. 岩石矿物学杂志. 2023; 42; (5). 663 - 672.

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