河南卢氏县拐峪采矿遗址出产绿松石的Sr、Pb同位素产地特征探析-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

河南卢氏县拐峪采矿遗址出产绿松石的Sr、Pb同位素产地特征探析

Origin characteristics of Sr and Pb isotopes of turquoise from Guaiyu mining site in Lushi County, Henan Province

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DOI	10.20086/j.cnki.yskw.2023.0206
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2023, 42(2)
作者	艾昊，先怡衡*，王英，于春，梁云，包伟柯，陈英，陈倩,
作者单位	1. 陕西省地质调查实验中心, 陕西西安 710065; 2. 文化遗产研究与保护技术教育部重点实验室, 西北大学, 陕西西安 710069; 3. 长沙市文物考古研究所, 湖南长沙 410000; 4. 河南省文物考古研究院, 河南郑州 450000; 5. 昭通市博物馆, 云南昭通 657000
摘要	河南卢氏县拐峪绿松石采矿遗址位于伊洛盆地西缘,该遗址的发现为研究中原早期绿松石的来源提供了重要的考古学信息。为判定该古矿产出绿松石的流向,尝试利用热电离质谱仪(TIMS)检测了拐峪古矿绿松石样品的Sr、Pb同位素组成,并结合秦岭5个主要绿松石矿的相关同位素数据,尝试寻找其产地特征。分析结果显示,拐峪绿松石⁸⁷Sr/⁸⁶Sr值相对较高,整体大于0.719 0,高于其他产地,可视为其产地特征之一;采用²⁰⁸Pb/²⁰⁴Pb-²⁰⁷Pb/²⁰⁸Pb联合示踪可得到较好的结果,在相关图解中拐峪绿松石具有独立的数据聚集区,可作为判断其产地证据之一;采用²⁰⁸Pb/²⁰⁴Pb-⁸⁷Sr/⁸⁶Sr和²⁰⁷Pb/²⁰⁸Pb-⁸⁷Sr/⁸⁶Sr联合示踪,也得到了较好的判别效果,拐峪绿松石与其他产地界线清晰,无明显重叠,表明Sr、Pb同位素组成是判断拐峪绿松石产地的重要证据。
Abstract	The Guaiyu turquoise mining site in Lushi, Henan Province is located in the western margin of the Yiluo Basin. The discovery of the mining site provides important archaeological information for the study of the provenience of turquoise in the early Central Plains. In order to determine the direction of the turquoise from the ancient mine, the Sr and Pb isotopic compositions of Guaiyu turquoise were detected by thermoelectric ionization mass spectrometer (TIMS). Combined with the isotopic data of five major turquoise deposits in Qinling Mountains, the provenience characteristics of turquoise from Guaiyu ancient mining site were explored. The results show that the ⁸⁷Sr/⁸⁶Sr ratio of Guaiyu turquoise is relatively high, which is greater than 0.719 0 on the whole, and higher than that of other turquoise deposit, which can be regarded as one of the characteristics of the Guaiyu turquoise. There is a high degree of overlap among Pb isotopic compositions, however, the ²⁰⁸Pb/²⁰⁴Pb-²⁰⁷Pb/²⁰⁸Pb diagram shows some independent data gathering areas,which can be used to judge the origin of the Guaiyu turquoise. In addition, combination of ²⁰⁸Pb/²⁰⁴Pb-⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁸Pb-⁸⁷Sr/⁸⁶Sr also obtained a good discrimination result, and the boundary with other regions is clear without obvious overlap. The Sr and Pb isotope composition is an important evidence to judge the origin of the Guaiyu turquoise.
关键词	卢氏县拐峪；绿松石；采矿遗址；Sr-Pb同位素；产地特征
KeyWord	Guaiyu of Lushi County; turquoise; mining site; Sr and Pb isotopes; origin characteristics
基金项目
页码	250-262

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相关文献

Alyson M T, Joaquin R, John T C, et al. 2007. Lead and strontium isotopes as tracers of turquoise
[J]. Soc. Archaeol Sci. Bull., 30:10~14. Alyson M T, Joaquin R, John T C, et al. 2009. Traceing Curquoise from Site to Source Using Radiogenic Isotopes
[M]. Society of American Archaeology, Atlanta, Georgia. Gong Wen. 2014. On the pendant of Yangshao Culture
[J]. Cultural Relics of Central China, 5:24~32(in Chinese with English abstract). Guo Qian and Xu Zhi. 2014. Progress in the study of color emerging mechanism of turquoise
[J]. Acta Petrologica et Mineralogica, 33(S1):136~140(in Chinese with English abstract). Hao Yongwei and Hao Feizhou. 2002. Turquoise culture in the Neolithic Age of China
[J]. Acat Petrologica et Mineralogica, 21(S1):147~150(in Chinese with English abstract). Jin Zhengyao. 2003. Achievements in applying Pb-isotope analysis to ancient Chinese bronzes
[J]. Acta Geoscientia Sinica, 24(6):548~551(in Chinese with English abstract). Jin Zhengyao. 2008. Lead Isotope Archaeology in China
[M]. Hefei:University of Science and Technology of China Press(in Chinese). Lei Tianting, Wang Zaicong and Li Yan. 2022. Copper isotopic variation of turquoise in low-temperature growth process and its significance for origin traceability
[J]. Editorial Committee of Earth Science-Journal of China University of Geosciences, 47(4):1 371~1 382(in Chinese with English abstract). Li Xintong, Xian Yiheng, Fan Jingyi, et al. 2019. Application of EMPA-XRD-SEM to study the mineralogical characteristics of turquoise from Xichuan, Henan Province
[J]. Rock and Mineral Analysis, 38(4):373~381(in Chinese with English abstract). Li Yanxiang and Xian Yiheng. 2015. Provenance studies of ancient turquoise in America
[J]. Sciences of Conservation and Archaeology, 27(2):102~109(in Chinese with English abstract). Li Yanxiang, Xian Yiheng, Chen Kunlong, et al. 2016. Investigation report of turquoise mine site in Luonan Estuary, Shaanxi Province
[J]. Archaeology and Cultural Relics, 3:11~17, 55(in Chinese with English abstract). Li Yanxiang, Zhang Dengyi, He Nu, et al. 2018. Exploration on origin characteristics of turquoise products unearthed from three pre-Qin sites in Shanxi
[J]. Cultural Relics, 2:86~91(in Chinese with English abstract). Liu Xifeng, Lin Chenlu, Li Dandan, et al. 2018. Study on mineralogy and spectroscopy of turquoises from Hami, Xinjiang
[J]. Spectroscopy and Spectral Analysis, 38(4):1 231~1 239(in Chinese with English abstract). Lu Xiaoke, Xu Changsong and Li Weidong. 2019. A study on raw material sources of white pottery based on analysis of strontium isotopes and trace elements
[J]. Huaxia Archaeology, 6:34~40(in Chinese with English abstract). Luo Yuanfei, Yu Xiaoyan, Zhou Yuegang, et al. 2017. A study of texture and structure of turquoise from Luonan, Shaanxi Province
[J]. Acta Petrologica et Mineralogica, 36(1):115~123(in Chinese with English abstract). Luo Zemin, Shen Xitian, Zhu Qinwen, et al. 2016. How structure compactness impacts the quantitative colour research of turquoise
[J]. Journal of Gem and Gemmology, 18(2):1~8(in Chinese with English abstract). Pin C, Gannoun A and Dupont A. 2014. Rapid, simultaneous separation of Sr, Pb, and Nd by extraction chromatography prior to isotope ratios determination by TIMS and MC-ICP-MS
[J]. J. Anal. At. Spectrom., 29:1 858~1 870. Ren Jia, Ye Xiaohong, Wang Yan, et al. 2015. Source constraints on turquoise of the Erlitou Site by infrared spectra
[J]. Spectroscopy and Spectral Analysis, 35(10):2 767~2 772(in Chinese with English abstract). Shi Zhenrong. 2008. Diagenetic origin of alphosphate-sulfate minerals in Cambrian Period carbon-silicon slate, Zhushan, Hubei
[J]. Jiangsu Geology, 32(2):109~112(in Chinese with English abstract). Shi Zhenrong and Cai Keqin. 2008. A study of turquoise and secondary woodhouseite from Yuertan, Baihe County, Shaanxi Province
[J]. Acta Petrologica et Mineralogica, 27(2):164~170(in Chinese with English abstract). Shi Zhenrong and Cai Keqin. 2011. A study of the origin of turquoise deposit in Zhushan County, Hubei Province
[J]. Acta Petrologica et Mineralogica, 30(Z1):187~194(in Chinese with English abstract). Tu Huaikui. 1996. Geological characteristics of turquoise ore in the areas adjacent to Shaanxi and Hubei provinces
[J]. Geology of Shaanxi, 14(2):59~64(in Chinese with English abstract). Tu Huaikui. 1997. Study on prospecting targets of turquois and uranium mineralization
[J]. Acta Geologica Gansu, (1):75~80(in Chinese with English abstract). Weiss D J, Kober B, Dolgopolova A, et al. 2004. Accurate and precise Pb isotope ratio measurements in environmental samples by MC-ICP-MS
[J]. Int. J. Mass Spectrom., 232:205~215. Wu Manlin and Yang Xiaoming. 2017. Application of strontium isotope tracing method in archaeological textile research
[J]. Journal of Silk, 54(5):51~54(in Chinese with English abstract). Xian Yiheng. 2016. The Studies on the Geographical Origin Characteristics of Turquoise from the Laziya Mine Sites in Luonan, Shannxi Province and the Surrounding Mine Areas
[D]. Beijing:University of Science and Technology Beijing(in Chinese with English abstract). Xian Yiheng, Fan Jingyi, Li Xintong, et al. 2018. Research on the source characteristics of Luonan turquoise by using strontium isotopic method
[J]. Northwestern Geology, 51(2):108~115(in Chinese with English abstract). Xian Yiheng, Li Yanxiang and Tan Yuchen. 2016a. Application of LA-ICP-AES to distinguish the different turquoise mines
[J]. Spectroscopy and Spectral Analysis, 36(10):3 313~3 319(in Chinese with English abstract). Xian Yiheng, Li Yanxiang and Yang Qihuang. 2016b. Principal component and portable X-ray fluorescence spectrometry analyses of the provenance of turquoise mines
[J]. Archaeology and Cultural Relics, 3:112~119(in Chinese with English abstract). Xian Yiheng, Liang Yun, Fan Jingyi, et al. 2021. Study on origin characteristics of turquoise from Hekou mining site in Luonan
[J]. Quaternary Sciences, 41(1):284~291(in Chinese with English abstract). Xu Yafen and Di Jingru. 2018. Gemological identification of natural turquoise and treatment turquoise in Hubei
[J]. Acta Petrologica et Mineralogica, 37(4):646~654(in Chinese with English abstract). Ye Xiaohong, Ren Jia and Xu Hong. 2014. A preliminary study on geological provenance of turquoise artifacts from erlitou site
[J]. Quaternary Sciences, 34(1):212~223(in Chinese with English abstract). Yin Ruochun. 2008. Prehistoric Human Migration in Jiahu Relics:Evidence from Strontium Isotope Analysis
[D]. Hefei:University of Science and Technology of China(in Chinese with English abstract). Zhang Benren, Li Zejiu, Luo Tingchuan, et al. 1987. Regional Geochemical Study of Lushi-Lingbao District, Western Henan
[M]. Beijing:Geological Publishing House(in Chinese). Zhang Dengyi. 2016. Determining the Provenance of pre-Qin Turquoise artifacts in Central China
[D]. Beijing:University of Science and Technology Beijing(in Chinese with English abstract). Zhao Chunyan. 2019. Research on the ancient people migration activities with the strontium isotope analysis technology
[J]. Northern Cultural Relics, 3:43~49(in Chinese with English abstract). Zhao Hongxia, Fu Xiufeng, Gan Fuxi, et al. 2007. Study on mineralogical characteristics of turquoise samples from different provenances by nondistrctive analysis
[J]. Rock and Mineral Analysis, 26(2):141~144(in Chinese with English abstract). Zhou Xiaojing. 2014. The Study of Jade of Hongshan Culture
[D]. Changchun:Jilin Universtiy(in Chinese with English abstract). 巩文. 2014. 仰韶文化坠饰述论
[J]. 中原文物, 5:24~32. 郭倩, 徐志. 2014. 我国绿松石致色机理研究进展
[J]. 岩石矿物学杂志, 33(S1):136~140. 郝用威, 郝飞舟. 2002. 中国新石器时代绿松石文化
[J]. 岩石矿物学杂志, 21(S1):147~150. 金正耀. 2003. 铅同位素示踪方法应用于考古研究的进展
[J]. 地球学报, 24(6):548~551. 金正耀. 2008. 中国铅同位素考古
[M]. 合肥:中国科学技术大学出版社. 雷天婷, 汪在聪, 李妍. 2022. 绿松石低温生长过程中Cu同位素特征及其对产地溯源的意义
[J]. 地球科学,47(4):1 371~1 382. 李欣桐,先怡衡,樊静怡,等. 2019. 应用扫描电镜-X射线衍射-电子探针技术研究河南淅川绿松石矿物学特征
[J]. 岩矿测试, 38(4):373~381. 李延祥,先怡衡. 2015. 美国古代绿松石示踪研究
[J]. 文物保护与考古科学, 27(2):102~109. 李延祥, 先怡衡, 陈坤龙,等. 2016. 陕西洛南河口绿松石矿遗址调查报告
[J]. 考古与文物,3:11~17, 55. 李延祥, 张登毅, 何驽,等. 2018. 山西三处先秦遗址出土绿松石制品产源特征探索
[J]. 文物, 2:86~91. 刘喜锋,林晨露,李丹丹,等. 2018. 新疆哈密绿松石的矿物学和光谱学特征研究
[J]. 光谱学与光谱分析, 38(4):1 231~1 239. 鲁晓珂, 徐嫦松, 李伟东. 2019. 基于锶同位素和微量元素分析的白陶原料来源研究
[J]. 华夏考古, 6:34~40. 罗远飞, 余晓艳,周越刚,等. 2017. 陕西洛南绿松石的结构构造特征研究
[J]. 岩石矿物学杂志,36(1):115~123. 罗泽敏,沈锡田,朱勤文,等. 2016. 绿松石结构的致密性对其颜色量化研究的影响
[J]. 宝石和宝石学杂志, 18(2):1~8. 任佳, 叶晓红, 王妍,等. 2015. 二里头遗址绿松石的红外光谱产地识别
[J]. 光谱学与光谱分析, 35(10):2 767~2 772. 石振荣. 2008. 湖北竹山寒武纪碳硅质板岩中蓝色似绿松石的特征分析
[J]. 江苏地质, 32(2):109~112. 石振荣,蔡克勤. 2008. 陕西白河县月儿潭绿松石与次生磷钙铝矾研究
[J]. 岩石矿物学杂志, 27(2):164~170. 石振荣,蔡克勤. 2011. 湖北省竹山县绿松石矿床成因研究
[J]. 岩石矿物学杂志, 30(Z1):187~194. 涂怀奎. 1996. 陕鄂相邻地区绿松石矿地质特征
[J]. 陕西地质,14(2):59~64. 涂怀奎. 1997. 绿松石与铀矿找矿方向的研究
[J]. 甘肃地质学报, (1):75~80. 吴曼琳,杨小明. 2017. 锶同位素溯源法在古代纺织品研究中的应用
[J]. 丝绸, 54(5):51~54. 先怡衡. 2016. 陕西洛南辣子崖采矿遗址及周边绿松石产源特征研究
[D]. 北京:北京科技大学. 先怡衡, 樊静怡, 李欣桐,等. 2018. 陕西洛南绿松石的锶同位素特征及其产地意义——兼论二里头出土绿松石的产源
[J]. 西北地质, 51(2):108~115. 先怡衡, 李延祥, 谭宇辰. 2016a. 初步运用LA-ICP-AES区分不同产地的绿松石
[J]. 光谱学与光谱分析, 36(10):3 313~3 319. 先怡衡, 李延祥, 杨岐黄. 2016b. 便携式X荧光光谱结合主成分分析鉴别不同产地的绿松石
[J]. 考古与文物, 3:112~119. 先怡衡, 梁云, 樊静怡,等. 2021. 洛南河口遗址出产绿松石产地特征研究
[J]. 第四纪研究, 41(1):284~291. 徐娅芬, 狄敬如. 2018. 湖北天然绿松石与优化处理绿松石的宝石学鉴别特征
[J]. 岩石矿物学杂志, 37(4):646~654. 叶晓红, 任佳, 许宏,等. 2014. 二里头遗址出土绿松石器物的来源初探
[J]. 第四纪研究, 34(1):212~223. 尹若春. 2008. 锶同位素分析技术在贾湖遗址人类迁移行为研究中的应用
[D]. 合肥:中国科学技术大学. 张本仁,李泽九,骆庭川,等. 1987. 豫西卢氏-灵宝地区区域地球化学研究
[M]. 北京:地质出版社. 张登毅. 2016. 中原先秦绿松石制品产源探索
[D]. 北京:北京科技大学. 赵春燕. 2019. 锶同位素分析技术追踪古人类迁移活动的研究
[J]. 北方文物,3:43~49. 赵虹霞,伏修锋,干福熹,等. 2007. 不同产地绿松石无损检测及岩相结构特征研究
[J]. 岩矿测试, 26(2):141~144. 周晓晶. 2014. 红山文化玉器研究
[D]. 长春:吉林大学.

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艾昊，先怡衡*，王英，于春，梁云，包伟柯，陈英，陈倩. 河南卢氏县拐峪采矿遗址出产绿松石的Sr、Pb同位素产地特征探析 [J]. 岩石矿物学杂志. 2023; 42; (2). 250 - 262.

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