钾长石水热制备钾霞石体系滤液循环实验研究-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

钾长石水热制备钾霞石体系滤液循环实验研究

Experimental study on circulation of filtrate of potassium feldspar hydrothermal preparation of kaliophilite system

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DOI	10.20086/j.cnki.yskw.2025.4173
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2025, 44(1)
作者	霍光祥，路华龙，段永华*，勾明雷，高嘉屿，陈紫宛,
作者单位	河南科技大学化学化工学院, 河南洛阳 471000
摘要	为提高水热法制备钾霞石工艺中钾长石硅的利用率及解决该工艺所产生的碱性废液问题,本研究进行了钾长石水热制备钾霞石体系滤液循环实验,探讨了反应时间、反应温度、硅铝比SiO₂与Al(OH)₃的摩尔比、碱浓度对硅的利用率及产物结构的影响,并对反应历程进行了探究。通过对最优条件下的滤液进行循环实验,探究了循环次数对硅的利用率、产物结构以及工艺稳定性的影响规律,并对改进前后的工艺流程作了对比。结果表明,当反应时间4.0 h、反应温度280℃、硅铝比0.8、碱浓度12 mol/L时,钾长石中硅的利用率可达94.2%,较工艺改进前提高了60%,产物钾霞石物相均一、品质优异,循环工艺稳定。
Abstract	To enhance the utilization ratio of silicon from potassium feldspar in the hydrothermal synthesis process of kaliophilite and address the issue of alkaline waste liquid produced by this process, this research carried out the filtrate recycling experiment in the hydrothermal synthesis system of potassium feldspar to kaliophilite. The effects of reaction time, reaction temperature, the molar ratio of SiO₂ to Al(OH)₃ and alkali concentration on Si utilization and product structure were discussed, as well as by investigating the reaction process. The effect of the number of cycles on the utilization ratio of silicon, the structure of the product and the stability of the process were investigated by the circulating experiment of the filtrate under the optimal conditions. The reaction mechanism was further explored and the process before and after the improvement was compared. The results demonstrate that when the reaction time was 4.0 h, the reaction temperature was 280℃, the molar ratio of SiO₂ to Al(OH)₃ was 0.8, and the alkali concentration was 12 mol/L, the utilization ratio of silicon in potassium feldspar could attain 94.2%, representing an increase of 60% compared to the process was improved. The product kaliophilite was homogeneous, superior quality and the recycling process was stable.
关键词	钾长石；水热法；钾霞石；循环滤液；利用率；稳定性
KeyWord	potassium feldspar; hydrothermal method; kaliophilite; circulating filtrate; utilization ratio; stability
基金项目
页码	207-215

参考文献
相关文献

Che Donghui, Li Zhenhua and Gao Jianguo. 1997. Improvement of roasting process of synthetic potassium nepheline
[J]. Qilu Petrochemical Technology, 25(4): 13~15 (in Chinese with English abstract). Fu J X, Zhao Y J, Chen J G, et al. 2021. Study on the integrated roasting process of kalsilite ore-CaCl₂·2 H₂O system
[J]. Minerals Engineering, 172(1): 106 996~107 009. He Y P, Zhang J Y, Chen H, et al. 2019. Low-energy synthesis of kaliophilite catalyst from circulating fluidized bed fly ash for biodiesel production
[J]. Fuel, 257(12): 1~10. Li Wenchao and Zhang Ning. 2023.Study on the determination of aluminum content in aluminum electrolyte by EDTA volumetric method
[J]. World Nonferrous Metals, 30(6): 112~114 (in Chinese with English abstract). Li Xiaoyan, Wan Fuwei, Peng Xueping, et al. 2015. Study on mineral composition of calcined potassium feldspar to produce silica-calc-potassium fertilizer
[J]. Bulletin of the Chinese Ceramic Society, 34(12): 3 648~3 651, 3 669 (in Chinese with English abstract). Liang Shidong, Li Xiaoyan, Wan Fuwei, et al. 2020. Experimental study on preparation of silica-calcium potassium fertilizer by calcination of potassium feldspar with different grades
[J]. Non-metallic Minerals, 43(5): 1~4 (in Chinese with English abstract). Liu X H, Jiang J P, Zhang H L, et al. 2020. Thermal stability and microstructure of metakaolin-based geopolymer blended with rice husk ash
[J]. Applied Clay Science, 196(10): 1~12. Ma Hongwen, Shen Jixue, Yang Jing, et al. 2017. Hydrolyzation-hydrothermal crystallization of nano-kaolinite
[J]. Journal of the Chinese Ceramic Society, 45(5): 722~728 (in Chinese with English abstract). Ma Hongwen, Yang Jing, Zhang Pan, et al. 2018. Reaction principle of potassium-rich syenite resources and potassium-salt production by hydrothermal alkali method in China
[J]. Earth Science Frontiers, 25(5): 277~285 (in Chinese with English abstract). Reziwanguli Y, Palidan A, Taximaiti Y, et al. 2023. Preparation of novel KAlSiO₄: Ce³⁺ broadband cyan-emitting phosphors via partial cation substitution for applications in white-light LEDs
[J]. Ceramics International, 49(10): 19~28. Ru Guangchuan, Li Cuiyan, Zhou Zhenfeng, et al. 2017. A method for preparing potassium nepheline by microwave activation of potassium feldspar and the potassium nepheline prepared by the method
[P]. Shaanxi Province: CN201610214396.9,2017-12-26 (in Chinese with English abstract). Song Q, Zhang H B, Shao J, et al. 2014. Preparation and characterization of Eu³⁺ doped Na₂O-Nb₂O₅-SiO₂ transparent glass-ceramics
[J]. Gongneng Cailiao, 45(17): 36~39. Su Shuangqing, Ma Hongwen, Yang Jing, et al. 2012. Hydrothermal synthesis of hexagonal-potassium nepheline from microcline powder and its characterization
[J]. Journal of the Chinese Ceramic Society, 40(1): 145~148 (in Chinese with English abstract). Su Shuangqing, Ma Hongwen, Yang Jing, et al. 2013. Hydrothermal synthesis of hexagonal-potassium nepheline from potassium feldspar powder
[P]. Beijing: CN201010543249.9, 2013-04-10 (in Chinese with English abstract). Xiong Zenghua and Wang Shijun. 2020. Review on development technology and industry of potassium resources in China
[J]. Conservation and Utilization of Mineral Resources, 40(6): 1~7 (in Chinese with English abstract). Xu Delong, Xu Liang, Xue Qunhu, et al. 2013. Feasibility study on co-production process of potash fertilizer and cement using potash feldspar as raw material
[J]. Bulletin of the Chinese Ceramic Society, 32(2): 181~185(in Chinese with English abstract). Zhang Yansong. 2023. Research on the Security Situation and Global Governance of China's Potassium Salt Resources
[D]. Wuhan: China University of Geosciences (Wuhan) (in Chinese with English abstract). Zhang Yongsheng and Zheng Mianping. 2021. Metallogenic regularity and deep exploration technology demonstration of potash salt mineral bases in China
[J]. Earth Science Frontiers, 28(6): 1~9 (in Chinese with English abstract). Zheng Ji and Ma Hongwen. 2006. Preparation and characterization of potassium nepheline by rapid sol-gel method
[J]. Acta Petrologica et Mineralogica, 25(4): 341~344 (in Chinese with English abstract). Zheng Ji and Ma Hongwen. 2007. Preparation of potassium nepheline by fast sol-gel method and its reaction mechanism
[J]. Chinese Journal of Engineering, 53(1): 55~58 (in Chinese with English abstract). 附中文参考文献车东晖, 李振华, 高建国. 1997. 合成钾霞石焙烧工艺的改进
[J]. 齐鲁石油化工, 25(4): 13~15. 梁世栋, 李小燕, 万夫伟, 等. 2020.煅烧不同品位钾长石制备硅钙钾肥试验研究
[J]. 非金属矿, 43(5): 1~4. 李文超, 张宁. 2023. EDTA容量法测定铝电解质中铝含量的方法研究
[J]. 世界有色金属, 30(6): 112~114. 李小燕, 万夫伟, 彭学平, 等. 2015. 煅烧钾长石生产硅钙钾肥的矿物组成研究
[J]. 硅酸盐通报, 34(12): 3 648~3 651, 3 669. 马鸿文, 申继学, 杨静, 等. 2017. 钾霞石酸解-水热晶化纳米高岭石
[J]. 硅酸盐学报, 45(5): 722~728. 马鸿文, 杨静, 张盼, 等. 2018. 中国富钾正长岩资源与水热碱法制取钾盐反应原理
[J]. 地学前缘, 25(5): 277~285. 茹广川, 李翠艳, 周镇峰, 等.2017. 一种钾长石微波活化制备钾霞石的方法及该方法制备的钾霞石
[P]. 陕西省: CN201610214396.9,2017-12-26. 苏双青, 马鸿文, 杨静, 等. 2012. 微斜长石粉体水热合成六方钾霞石及其表征
[J]. 硅酸盐学报, 40(1): 145~148. 苏双青, 马鸿文, 杨静, 等. 2013. 利用钾长石粉体水热合成六方钾霞石的方法
[P]. 北京市: CN201010543249.9,2013-04-10. 熊增华, 王石军. 2020. 中国钾资源开发利用技术及产业发展综述
[J]. 矿产保护与利用, 40(6): 1~7. 徐德龙, 徐亮, 薛群虎, 等. 2013. 以钾长石为原料钾肥-水泥联产工艺可行性研究
[J]. 硅酸盐通报, 32(2): 181~185. 张艳松. 2023. 中国钾盐资源安全态势与全球治理研究
[D]. 武汉: 中国地质大学(武汉). 张永生, 郑绵平. 2021. 中国钾盐矿产基地成矿规律与深部探测技术示范
[J]. 地学前缘, 28(6): 1~9. 郑骥, 马鸿文. 2006. 钾霞石快速溶胶-凝胶法制备及表征
[J]. 岩石矿物学杂志, 25(4): 341~344. 郑骥, 马鸿文. 2007. 快速溶胶凝胶法制备钾霞石及其反应机理
[J]. 北京科技大学学报, 53(1): 55~58.

引用本文

霍光祥，路华龙，段永华*，勾明雷，高嘉屿，陈紫宛. 钾长石水热制备钾霞石体系滤液循环实验研究 [J]. 岩石矿物学杂志. 2025; 44; (1). 207 - 215.

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