飞行时间二次离子质谱(TOF-SIMS)在矿物包裹体研究中的应用-岩石矿物学杂志-CSCIED科技核心评价数据库-手机版

飞行时间二次离子质谱(TOF-SIMS)在矿物包裹体研究中的应用

Application of time-of-flight secondary ion mass spectrometry (TOF-SIMS) in the study of mineral inclusions

ES评分 0 浏览量：301 下载量：0

DOI	10.20086/j.cnki.yskw.2023.0310
刊名	岩石矿物学杂志 Acta Petrologica et Mineralogica
年，卷(期)	2023, 42(3)
作者	王梦琴，蔡克大，李展平*,
作者单位	1. 中国地质大学地球科学与资源学院, 地质过程与矿产资源国家重点实验室, 北京 100083; 2. 清华大学化学系, 有机光电子与分子工程教育部重点实验室, 北京 100084
摘要	矿物包裹体的化学成分研究在地质学、矿床学和油气勘探等方面具有重要意义。目前对包裹体化学成分分析的主要分析方法有激光烧蚀电感耦合等离子体质谱(LA-ICP-MS)、电子探针(EPMA)、显微激光拉曼光谱(LRS)、傅里叶变换红外光谱(FTIR)、质子诱发X射线光谱分析(PIXE)、同步辐射X射线荧光光谱(SXRF)和(传统的)二次离子质谱分析(SIMS)等。本文在对上述方法的分析特点进行简单介绍的基础上,重点阐述了对于矿床学样品表征具有广泛应用潜力的飞行时间二次离子质谱(TOF-SIMS)的原理、特点和技术优势,总结了国内外学者应用TOF-SIMS对矿物包裹体化学成分分析的研究进展与存在问题,并做了相关领域的展望。
Abstract	The study of the chemical composition of mineral inclusions is of great significance in geology, mineralogy, and hydrocarbon exploration. The main methods currently investigated for the analysis of the chemical composition of inclusions are laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), electron probe microanalysis (EPMA), laser Raman spectroscopy (LRS), Fourier transform infrared spectroscopy (FTIR), proton-induced X-ray emission spectroscopy (PIXE), synchrotron X-ray fluorescence spectroscopy (SXRF) and (conventional) secondary ion mass spectrometry (SIMS), etc. This paper briefly introduces the analytical characteristics of the above methods, focuses on the principles, characteristics, and technical advantages of time-of-flight secondary ion mass spectrometry (TOF-SIMS), which has wide potential for the characterization of mineralogical samples, and summarizes the progress and problems of the application of TOF-SIMS for the analysis of the chemical composition of mineral inclusions by domestic and foreign scholars, and gives an outlook on related fields.
关键词	矿物包裹体；TOF-SIMS；表面分析
KeyWord	mineral inclusion; TOF-SIMS; surface analysis
基金项目
页码	451-464

参考文献
相关文献

Audétat A and Lowenstern J B. 2014. Melt inclusions
[C]// Treatise on Geochemistry(Second Edition), 13: 143~173. Cadd S, Islam M, Manson P, et al. 2015. Fingerprint composition and aging: A literature review
[J]. Science & Justice, 55 (4): 219~238. Chelgani S C and Hart B. 2014. TOF-SIMS studies of surface chemistry of minerals subjected to flotation separation-A review
[J]. Minerals Engineering, 57: 1~11. Chen Anfu. 1985. Application of the mole Raman spectroscopy for analysis of individual phases in fluid inclusion in minerals
[J]. Acta Petrologica et Mineralogica, 4 (3): 231~237, 287(in Chinese with English abstract). Frezzotti M L, Tecce F and Casagli A. 2012. Raman spectroscopy for fluid inclusion analysis
[J]. Journal of Geochemical Exploration, 112: 1~20. Galuska A A. 2001. Quantitative TOF-SIMS analysis of monomers, oxidation and trace elements in EPDM gels
[J]. Surface and Interface Analysis, 31 (3): 177~184. Günther D, Audétat A, Frischknecht R, et al. 1998. Quantitative analysis of major, minor and trace elements in fluid inclusions using laser ablation-inductively coupled plasmamass spectrometry
[J]. Journal of Analytical Atomic Spectrometry, 13 (4): 263~270. Horn E E and Traxel K. 1987. Investigations of individual fluid inclusions with the Heidelberg proton microprobe—A nondestructive analytical method
[J]. Chemical Geology, 61 (1~4): 29~35. Humphreys M C S, Kearns S L and Blundy J D. 2006. SIMS investigation of electron-beam damage to hydrous, rhyolitic glasses: Implications for melt inclusion analysis
[J]. American Mineralogist, 91 (4): 667~679. Jin Binghui and Sun Luren. 1983. Reference samples for elecptron microrobe analysis
[J]. Acta Petrologica et Mineralogica, 2(3): 206~209 (in Chinese with English abstract). Kent A J R. 2008. Melt inclusions in basaltic and related volcanic rocks
[J]. Reviews in Mineralogy and Geochemistry, 69 (1): 273~331. Kia A M, Haufe N, Esmaeili S, et al. 2019. ToF-SIMS 3D analysis of thin films deposited in high aspect ratio structures via atomic layer deposition and chemical vapor deposition
[J]. Nanomaterials, 9(7): 1 035. Li Dapeng, Du Yangsong, Scott S D, et al. 2012. Melt inclusion of sulfide in mantal-driven amphibole megacrysts
[J]. Acta Geologica Sinica, 86 (7): 1 091~1 105(in Chinese with English abstract). Li R X and Parnell J. 2003. In situ microanalysis of petroleum fluid inclusions by time of flight-secondary ion mass spectrometry as an indicator of evolving oil chemistry: A pilot study in the Bohai Basin, China
[J]. Journal of Geochemical Exploration, 78: 377~384. Li Rongxi and Zhou Shengbin. 2000. Analytical techniques for individual organic inclusions and the application of TOF-SIMS
[J]. Acta Mineralogica Sinica, 20(2): 172~176(in Chinese with English abstract). Li Zhanping. 2020. Time-of-flight secondary ion mass spectrometry
[J]. Bulletin of Mineralogy, Petroloy and Geochemistry, 39 (6): 1 173~1 190(in Chinese with English abstract). Liu Y S, Hu Z C, Li M, et al. 2013. Applications of LA-ICP-MS in the elemental analyses of geological samples
[J]. Chinese Science Bulletin, 58 (32): 3 863~3 878. Lu Huanzhang, Fan Hongrui, Ni Pei, et al. 2004. Fluid Inclusion
[M]. Beijing: Science Press, 11~33 (in Chinese). Marques A F A, Scott S D and Sodhi R N S. 2011. Determining major and trace element compositions of exposed melt inclusions in minerals using ToF-SIMS
[J]. Surface and Interface Analysis, 43 (1~2): 436~442. Marques A F A, Scott S D and Sodhi R N S. 2012. Time-of-Flight SIMS (ToF-SIMS) Analyses of Melt Inclusions
[J]. The Canadian Mineralogist, 50(5): 1 305~1 320. Mason P R D, Nikogosian I K and van Bergen M J. 2008. Major and trace element analysis of melt inclusions by laser ablation ICP-MS
[C]//Laser Ablation ICP-MS in the Earth Sciences: Current Practices and Outstanding Issues. Mineralogical Association of Canada Short Course Series, Canada, 40: 219~240. Metzner R, Schneider H U, Breuer U, et al. 2008. Imaging nutrient distributions in plant tissue using time-of-flight secondary ion mass spectrometry and scanning electron microscopy
[J]. Plant Physiology, 147 (4): 1 774~1 787. Natalio F, Corrales T P, Pierantoni M, et al. 2021. Characterization of Eocene flint
[J]. Chemical Geology, 582: 120427. Nichols A R L and Wysoczanski R J. 2007. Using micro-FTIR spectroscopy to measure volatile contents in small and unexposed inclusions hosted in olivine crystals
[J]. Chemical Geology, 242 (3): 371~384. Ni Pei, Fan Hongrui, Pan Junyi, et al. 2021. Progress and prospect of fluid inclusion research in the past decade in China (2011~2020)
[J]. Bulletin of Mineralogy, Petroloy and Geochemistry, 40 (4): 802~818(in Chinese with English abstract). North R, Tanner D, Nancarrow M, et al. 2022. Resolving sub-micrometer-scale zonation of trace elements in quartz using TOF-SIMS
[J]. American Mineralogist, 107 (5): 955~969. Pettke T, Halter W E, Webster J D, et al. 2004. Accurate quantification of melt inclusion chemistry by LA-ICPMS: A comparison with EMP and SIMS and advantages and possible limitations of these methods
[J]. Lithos, 78 (4): 333~361. Rinnen S, Stroth C, Riвe A, et al. 2015. Characterization and identification of minerals in rocks by ToF-SIMS and principal component analysis
[J]. Applied Surface Science, 349: 622~628. Roedder E. 1984. Fluid inclusions
[C]//Reviews in Mineralogy, 12: 644. Rossi A, Elsener B, Hähner G, et al. 2000. XPS, AES and ToF-SIMS investigation of surface films and the role of inclusions on pitting corrosion in austenitic stainless steels
[J]. Surface and Interface Analysis, 29 (7): 460~467. Rost D, Fritz J, Greshake A, et al. 2003. Investigation of a brown weathering product found in Nakhla melt inclusions
[J]. Meteoritics and Planetary Science Supplement, 38: 5 243. Rost D, Fritz J, Greshake A, et al. 2002. Characterization of Melt Inclusions in Martian Meteorites by Using TOF-SIMS, EMPA, and SEM
[J]. Meteoritics and Planetary Science Supplement, 37: A122. Rost D, Greshake A, Stephan T, et al. 2001. First results from a comprehensive study of melt inclusions in Martian meteorites
[J]. Meteoritics and Planetary Science Supplement, 36: A177. Schirmeyer S, Hoppe P, Stephan T, et al. 1997. A lithium-bearing Ca, Al-rich inclusion from the CM-chondrite Cold Bokkeveld studied by TOF-SIMS and conventional SIMS
[C]//The 28th Lunar and Planetary Science Conference. Houston, 28: 253. Seyfang K E, Lucas N, Popelka-Filcoff R S, et al. 2019. Methods for analysis of glass in glass-containing gunshot residue (gGSR) particles
[J]. Forensic Science International, 298: 359~371. Siljeström S, Hode T, Lausmaa J, et al. 2009. Detection of organic biomarkers in crude oils using ToF-SIMS
[J]. Organic Geochemistry, 40 (1): 135~143. Siljestrom S, Lausmaa J, Sjovall P, et al. 2010. Analysis of hopanes and steranes in single oil-bearing fluid inclusions using time-of-flight secondary ion mass spectrometry (ToF-SIMS)
[J]. Geobiology, 8 (1): 37~44. Siljeström S, Volk H and George S C. 2022. Using ToF-SIMS analyses for analysing individual oil inclusions of different fluorescence colours in a single quartz crystal from the Barrandian (Czech Republic)
[J]. Organic Geochemistry, 164: 104354. Siljeström S, Volk H, George S C, et al. 2013. Analysis of single oil-bearing fluid inclusions in mid-Proterozoic sandstones (Roper Group, Australia)
[J]. Geochimica et Cosmochimica Acta, 122: 448~463. Stephan T. 2001. TOF-SIMS in cosmochemistry
[J]. Planetary and Space Science, 49 (9): 859~906. Tacchetto T, Reddy S M, Bartoli O, et al. 2021. Pre-nucleation geochemical heterogeneity within glassy anatectic inclusions and the role of water in glass preservation
[J]. Contributions to Mineralogy and Petrology, 176 (9): 70. Taylor R P, Jackson S E, Longerich H P, et al. 1997. In situ trace-element analysis of individual silicate melt inclusions by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS)
[J]. Geochimica et Cosmochimica Acta, 61(13): 2 559~2 567. Thiel V, Lausmaa J, Sjovall P, et al. 2016. Microbe-like inclusions in tree resins and implications for the fossil record of protists in amber
[J]. Geobiology, 14 (4): 364~373. Thiel V and Sjövall P. 2011. Using time-of-flight secondary ion mass spectrometry to study biomarkers
[J]. Annual Review of Earth and Planetary Sciences, 39 (1): 125~156. Wen S M, Liu J and Deng J S. 2021. Fluid Inclusion Effect in Flotation of Sulfide Minerals
[M]. Elsevier, 27~68. Wysoczanski R and Tani K. 2006. Spectroscopic FTIR imaging of water species in silicic volcanic glasses and melt inclusions: An example from the Izu-Bonin arc
[J]. Journal of Volcanology and Geothermal Research, 156 (3): 302~314. Xia Linqi. 2002. Melt inclusions in magmatic rocks
[J]. Earth Science Frontiers, 9 (2): 403~414 (in Chinese with English abstract). Xiong Fahui, Xu Xiangzhen, Yang Shengbiao, et al. 2022. Genesis and significance of different types of mineral inclusions in podiform chromitite
[J]. Acta Petrologica et Mineralogica, 41(2): 413~436(in Chinese with English abstract). Zhang Chunlai, Liu Yongsheng, Gao Shan, et al. 2011. Chemical compositions of phenocryst-hosted melt inclusions from the Sihetun basalt: Implications for the magma evolution
[J]. Geochimica, 40 (2): 109~125 (in Chinese with English abstract). Zolensky M, Bodnar R J, Dolocan A, et al. 2020. Direct analysis of early solar system aqueous fluids
[C]//The 11th Symposium on Polar Science. Tokyo, Japan. Zolensky M E, Bodnar R J, Yurimoto H, et al. 2017. The search for and analysis of direct samples of early solar system aqueous fluids
[C]//Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 375 (2094): 20150386. 陈安福. 1985. 拉曼光谱在矿物包裹体成分分析中的应用
[J]. 岩石矿物学杂志, 4(3): 231~237, 287. 金秉慧, 孙鲁仁. 1983. 电子探针矿物定量分析用标准参考样品
[J]. 岩石矿物学杂志, 2(3): 206~209. 李大鹏, 杜杨松, Scott S D, 等. 2012.幔源角闪石巨晶中硫化物熔融包裹体研究
[J]. 地质学报, 86 (7): 1 091~1 105. 李荣西, 周生斌. 2000.矿物中单个有机包裹体测试与TOF-SIMS技术的应用
[J]. 矿物学报, 20 (2): 172~176. 李展平.2020. 飞行时间二次离子质谱(TOF-SIMS)分析技术
[J]. 矿物岩石地球化学通报, 39 (6): 1 173~1 190. 卢焕章, 范宏瑞, 倪培, 等. 2004. 流体包裹体
[M]. 北京: 科学出版社, 11~33. 倪培, 范宏瑞, 潘君屹, 等. 2021. 流体包裹体研究进展与展望(2011-2020)
[J]. 矿物岩石地球化学通报, 40 (4): 802~818. 夏林圻. 2002. 岩浆岩中的熔体包裹体
[J]. 地学前缘, 9 (2): 403~414. 熊发挥, 徐向珍, 杨胜标, 等. 2022. 豆荚状铬铁矿中不同类型矿物包裹体成因及指示意义
[J]. 岩石矿物学杂志, 41(2): 413~436. 张春来, 刘勇胜, 高山, 等. 2011. 四合屯玄武岩斑晶中单个熔体包裹体元素组成及其对岩浆演化的指示
[J]. 地球化学, 40 (2): 109~125.

引用本文

王梦琴，蔡克大，李展平*. 飞行时间二次离子质谱(TOF-SIMS)在矿物包裹体研究中的应用 [J]. 岩石矿物学杂志. 2023; 42; (3). 451 - 464.

文献评论

相关学者

相关机构