高盐废水中钙镁离子的碳化处理工艺研究进展

Research progress on carbonization treatment of calcium and magnesium ions in high-salinity wastewater

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DOI 10.12208/j.jccr.20240003
刊名
Journal of Chemistry and Chemical Research
年,卷(期) 2024, 4(1)
作者
作者单位

1 四川轻化工大学化学工程学院 四川自贡 ;
;
2 重庆工商大学环境与资源学院 重庆 ;

摘要
含有钙镁离子的高盐废水处理与很多化工相关企业都息息相关。如果治理不好,不仅污染环境和危害人类健康,还严重浪费资源。钙镁离子高盐废水的资源化回收利用,已成为急需攻关的关键科学/工程技术问题。二氧化碳沉淀钙镁离子,既有助于实现双碳目标,又为二氧化碳的捕集与利用探索出新的研究领域和方向。为此,本文综述了近年来,用含钙镁离子高盐废水捕集二氧化碳,并回收具有高附加值碱式碳酸镁、碳酸钙等产品的工艺研究进展。展望了反应过程机理研究中,在线检测技术应用;海水/盐湖卤水直捕空气中的二氧化碳或海/湖储存二氧化碳等方面研究。本综述有望帮助相关科研单位,尤其是对同时排放二氧化碳和钙镁离子的高盐废水的相关企业有极大参考借鉴意义。此外,该综述有助于持续优化提升含有钙镁离子的高盐废水捕集二氧化碳的相关研究。
Abstract
The treatment of wastewater containing high concentrations of calcium and magnesium ions is closely related to many chemical-related companies. The discharge of non-treated wastewater containing high concentrations of calcium and magnesium ions not only pollutes the environment and endangers human health, but also seriously wastes resources. The precipitation of calcium and magnesium ions by CO2 is conductive to achieving the dual-carbon goal, besides exploring new research fields and directions for the capture, utilization and storage of CO2 (CCUS). To this end, this paper reviews the progress on the process of CO2 capturing with wastewater containing high concentrations of calcium and magnesium ions to get high value-added alkaline magnesium carbonate and calcium carbonate. The research on the mechanism of precipitation of calcium and magnesium ions by CO2, the application of in-situ characterization technology and the direct capture or storage of CO2 by brine of seawater/salt-lake was also highlighted. This review is expected to be of great reference to help relevant research institutes, especially to companies that release CO2 and discharge wastewater containing high concentrations of calcium and magnesium ions. In addition, this review is expected to contribute to the continuous optimization and enhancement of CO2 capturing from wastewater containing high concentrations of calcium and magnesium ions.
关键词
高盐废水;钙镁离子分离;二氧化碳捕集;一次碳化;二次碳化
KeyWord
High-salt wastewater; Calcium and magnesium ion separation; Carbon dioxide capture; A carbonization; Secondary carbonization
基金项目
页码 5-11
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唐鹏*,田海洋,覃孝平*,李宁. 高盐废水中钙镁离子的碳化处理工艺研究进展 [J]. 化学与化工研究. 2024; 4; (1). 5 - 11.

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